784-36-1

Basic information

• Product Name: 1-phenylthio-2,3,5,6-tetrafluorobenzene
• Synonyms: 1-phenylthio-2,3,5,6-tetrafluorobenzene
• CAS NO: 784-36-1
• Molecular Weight: 258.239
• Mol File: 784-36-1.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 1-phenylthio-2,3,5,6-tetrafluorobenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-phenylthio-2,3,5,6-tetrafluorobenzene(784-36-1)
• EPA Substance Registry System: 1-phenylthio-2,3,5,6-tetrafluorobenzene(784-36-1)

Safety Data

• Hazardous Substances Data: 784-36-1(Hazardous Substances Data)

Upstream product

• 934-87-2 S-phenyl thioacetate 
• 363-72-4 Pentafluorobenzene 
• 882-33-7 diphenyldisulfane 
• 6485-79-6 chlorotriisopropylsilane 
• 16496-09-6 phenyl 2,3,4,5,6-pentafluorophenyl sulfide 
• 1402596-62-6 bis(4-benzoyl-2,3,5,6-tetrafluorophenyl) sulfide 
• 108-98-5 thiophenol 
• 32812-89-8 bis(benzenethiolato)lead(II) 
• 1559-88-2 1-bromo-2,3,5,6-tetrafluorobenzene 
• 1192-40-1 copper(I) thiophenolate 

Relevant articles and documents

Organocatalyzed Fluoride Metathesis

A new organocatalyzed fluoride metathesis reaction between fluoroarenes and carbonyl derivatives is reported. The reaction exchanges fluoride (F-) and alternate nucleophiles (OAc-, OCO2R-, SR-, Cl-, CN-, NCS-). The approach provides a conceptually novel route to manipulate the fluorine content of organic molecules. When the fluorination and defluorination steps are combined into a single catalytic cycle, a byproduct free and 100% atom-efficient reaction can be achieved.

Synthesis of unsymmetrical polyfluorinated diaryl sulfides by rhodium-catalyzed aryl exchange reaction

RhH(PPh3)4 and 1,2-bis(diphenylphosphino)benzene (dppBz) catalyze the aryl exchange reaction of polyfluorinated diaryl sulfides. By employing these catalysts, unsymmetrical polyfluorinated diaryl sulfides are synthesized by the react

THE THIOLATE ANION AS A NUCLEOPHILE. PART XIII. REACTIONS OF SOME TIN(II) AROMATIC THIOLATES

The reactions of tin(II) benzenethiolate and p-toluenethiolate with various fluoroaromatics in DMF have been studied.Replacement of some of the aromatic fluorines by the thiolate group was observed.The tin(II) aromatic thiolates are comparable in reactivity in these reactions with lead(II) benzenethiolate.All new compound have been characterized by elemental analysis, and NMR (H-1 and F-19) and mass spectroscopy.