785-86-4 Usage
Description
(1E)-1,3-bis(4-methylphenyl)triaz-1-ene, a triazene compound with the chemical formula C17H16N2, is characterized by a nitrogen-nitrogen double bond attached to an imino group. This yellow solid is recognized for its role in organic synthesis and as a precursor to other chemical compounds.
Uses
Used in Organic Synthesis:
(1E)-1,3-bis(4-methylphenyl)triaz-1-ene is utilized as a reagent in organic synthesis, contributing to the formation of various complex organic molecules. Its unique structure allows it to participate in a range of chemical reactions, facilitating the synthesis of desired products.
Used in Research:
In the realm of scientific research, (1E)-1,3-bis(4-methylphenyl)triaz-1-ene serves as a probe for detecting oxidative stress in biological systems. Its reactivity in the presence of reactive oxygen species makes it a valuable tool for studying oxidative processes and their impact on biological systems.
Used in Pharmaceutical Industry:
(1E)-1,3-bis(4-methylphenyl)triaz-1-ene holds potential applications in the pharmaceutical industry, where it may contribute to the development of new drugs. Its unique chemical properties could be harnessed to create novel therapeutic agents.
Used in Agricultural Industry:
Similarly, in the agricultural sector, this compound may find use in the development of new agrochemicals. Its potential role as a precursor to other compounds could lead to the creation of innovative products for crop protection and enhancement of agricultural yields.
Check Digit Verification of cas no
The CAS Registry Mumber 785-86-4 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 7,8 and 5 respectively; the second part has 2 digits, 8 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 785-86:
(5*7)+(4*8)+(3*5)+(2*8)+(1*6)=104
104 % 10 = 4
So 785-86-4 is a valid CAS Registry Number.
785-86-4Relevant articles and documents
N2 extrusion and co insertion: A novel palladium-catalyzed carbonylative transformation of aryltriazenes
Li, Wanfang,Wu, Xiao-Feng
supporting information, p. 1910 - 1913 (2015/04/27)
A novel procedure for the replacement of N2 with CO of aryltriazenes has been developed. Aryltriazenes were converted to the corresponding arylamides catalyzed by 1 mol % of PdCl2/P(o-Tol)3 under CO pressure. In this process, aryldiazonium salts were generated in the presence of 40 mol % of MeSO3H. Nitrogen was released from the substrates and CO formally inserted. Aryl bromides, iodides, alkynes, and free hydroxyl groups can be tolerated in this transformation.
Novel one-pot synthesis of thiophenols from related triazenes under mild conditions
Khazaei, Ardeshir,Kazem-Rostami, Masoud,Moosavi-Zare, Ahmadreza,Bayat, Mohammad,Saednia, Shahnaz
experimental part, p. 1893 - 1896 (2012/09/22)
In this work, at first, triazenes were synthesized from primary aryl amines. Afterwards, triazenes were converted into the corresponding thiophenols in one-pot using sodium sulfide in acidic media, by in situ generation of diazonium counterion beside hydrogen sulfide as anionic sulfur nucleophile at room temperature. The procedure can be a convenient shortcut for the preparation of thiophenols from primary aryl amines. Georg Thieme Verlag Stuttgart · New York.
Nitrogen dioxide - Sodium iodide as an efficient reagent for the one- pot conversion of aryl amines to aryl iodides under nonaqueous conditions
Suzuki, Hitomi,Nonoyama, Nobuaki
, p. 4533 - 4536 (2007/10/03)
Successive treatment of aromatic amines with liquid nitrogen dioxide and powdered sodium iodide in acetonitrile at -20 °C, followed by usual work- up, gave the corresponding aryl iodides in good yield. This method worked especially well for less basic amines bearing electron-withdrawing substituents.