78550-50-2

Basic information

• Product Name: Phenol, 2,2'-methylenebis[4-fluoro-
• CAS NO: 78550-50-2
• Molecular Formula: C13H10F2O2
• Molecular Weight: 236.218
• Mol File: 78550-50-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Phenol, 2,2'-methylenebis[4-fluoro-(CAS DataBase Reference)
• NIST Chemistry Reference: Phenol, 2,2'-methylenebis[4-fluoro-(78550-50-2)
• EPA Substance Registry System: Phenol, 2,2'-methylenebis[4-fluoro-(78550-50-2)

Safety Data

• Hazardous Substances Data: 78550-50-2(Hazardous Substances Data)

Upstream product

• 371-41-5 4-Fluorophenol 
• 19415-51-1 5-fluoro-2-methoxybenzaldehyde 
• 700381-18-6 2-(bromomethyl)-4-fluoro-1-methoxybenzene 
• 426831-32-5 (5-fluoro-2-methoxyphenyl)methanol 
• 50-00-0 formaldehyd 

Downstream Products

• 78563-34-5 Acetic acid 2-[2-acetoxy-3-(2-acetoxy-5-fluoro-benzoyl)-5-fluoro-benzoyl]-6-(2-acetoxy-5-fluoro-benzoyl)-4-fluoro-phenyl ester 
• 78563-31-2 Acetic acid 2-[2-acetoxy-3-(2-acetoxy-5-fluoro-benzyl)-5-fluoro-benzyl]-6-(2-acetoxy-5-fluoro-benzyl)-4-fluoro-phenyl ester 
• 83143-22-0 1,1-bis(2-acetoxy-5-fluorophenyl)ethanol 
• 83143-09-3 1-{3-[1-(3-Acetyl-5-fluoro-2-hydroxy-phenyl)-1-hydroxy-ethyl]-5-fluoro-2-hydroxy-phenyl}-ethanone 
• 83143-05-9 1-[3-(3-Acetyl-5-fluoro-2-hydroxy-benzoyl)-5-fluoro-2-hydroxy-phenyl]-ethanone 
• 78563-09-4 1-[3-(3-Acetyl-5-fluoro-2-hydroxy-benzyl)-5-fluoro-2-hydroxy-phenyl]-ethanone 
• 83143-19-5 Acetic acid 2-(2-acetoxy-5-fluoro-benzoyl)-4-fluoro-phenyl ester 
• 78563-30-1 C₂₇H₂₀F₄O₄ 
• 83153-63-3 Acetic acid 2-(2-acetoxy-5-fluoro-benzyl)-4-fluoro-phenyl ester 
• 71319-34-1 C₁₃H₈F₂N₂O₆ 

Relevant articles and documents

One-step novel synthesis of methylene bisphenols and methylene bisnaphthols using Lewis acid mediated rearrangement

Mono- and di-substituted isomeric methylene bisphenols and methylene bisnaphthols have been synthesized by rearrangement of the corresponding O-methoxyacetyl derivatives of phenols and naphthols, respectively, in presence of aluminium chloride under dry conditions. The chemistry observed is different from the usual Fries rearrangement reaction and involves an intermolecular rearrangement. The reactions reported here also reflect the influence of substituents present in the substrate as is supported by the substitution of the bridging methylene at a position meta to the phenolic hydroxyl in some of the minor products formed along-side the majorly formed ortho substituted products.

The Synthesis of Polyfunctional Aromatic Ring Systems. Structural Analogues of Phloroglucides, Aranciamycin, Cryptosporin and Terramycin

The synthesis of the title compounds is described.Some of the compounds prepared were found to be active against a number of pathogenic microorganisms in vitro.