78579-57-4

Basic information

• Product Name: N-(propan-2-yl)hexan-1-amine
• CAS NO: 78579-57-4
• Molecular Formula: C₉H₂₁N
• Molecular Weight: 143.2697
• Mol File: 78579-57-4.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 173.9°C at 760 mmHg
• Flash Point: 43.8°C
• Density: 0.769g/cm³
• Vapor Pressure: 1.24mmHg at 25°C
• Refractive Index: 1.421
• CAS DataBase Reference: N-(propan-2-yl)hexan-1-amine(CAS DataBase Reference)
• NIST Chemistry Reference: N-(propan-2-yl)hexan-1-amine(78579-57-4)
• EPA Substance Registry System: N-(propan-2-yl)hexan-1-amine(78579-57-4)

Safety Data

• Hazardous Substances Data: 78579-57-4(Hazardous Substances Data)

Upstream product

• 75-29-6 isopropyl chloride 
• 111-26-2 hexan-1-amine 
• 75-31-0 isopropylamine 
• 693-02-7 hex-1-yne 
• 643764-86-7 Hex-(E)-ylidene-isopropyl-amine 
• 66-25-1 hexanal 
• 32838-32-7 hexyl-isopropyliden-amine 

Relevant articles and documents

carba Nicotinamide Adenine Dinucleotide Phosphate: Robust Cofactor for Redox Biocatalysis

Here we report a new robust nicotinamide dinucleotide phosphate cofactor analog (carba-NADP+) and its acceptance by many enzymes in the class of oxidoreductases. Replacing one ribose oxygen with a methylene group of the natural NADP+ was found to enhance stability dramatically. Decomposition experiments at moderate and high temperatures with the cofactors showed a drastic increase in half-life time at elevated temperatures since it significantly disfavors hydrolysis of the pyridinium-N?glycoside bond. Overall, more than 27 different oxidoreductases were successfully tested, and a thorough analytical characterization and comparison is given. The cofactor carba-NADP+ opens up the field of redox-biocatalysis under harsh conditions.

Anti-Markovnikov Intermolecular Hydroamination: A Bis(amidate) Titanium Precatalyst for the Preparation of Reactive Aldimines

(Matrix presented) A bulky bis-(N-2′,6′- diisopropylphenyl(phenyl)-amidate)titanium-bis(diethylamido) complex was identified as a highly active and regioselective precatalyst for the anti-Markovnikov hydroamination of a wide range of terminal alkyl alkynes with alkylamines. This titanium complex was fully characterized, including its X-ray crystal structure. The reactive aldimine products generated have been further elaborated using one-pot procedures to give substituted amines, aldehydes, and the isoquinoline framework.

ELECTROCHEMICAL REDUCTIVE AMINATION. II. AMINATION OF ALIPHATIC ALDEHYDES WITH PRIMARY AMINES

The formation of a secondary amine by the electrolysis of an aqueous solution containing an aldehyde and a primary amine was studied.The formation of the secondary amines passes through the intermediate stage of an aldimine.The highest yield of secondary amine is attained at a molar ratio of primary amine to aldehyde of 1.2:1.As electrode material lead, cadmium, zinc, and copper may be used.As supporting electrolyte a phosphate buffer with a pH close to the pKa of the primary amine is recommended.By the method developed 32 amines with various structures were synthesized.