78725-90-3

Basic information

• Product Name: O-ethyl S-phenyl carbonothioate
• CAS NO: 78725-90-3
• Molecular Formula: C₉H₁₀O₂S
• Molecular Weight: 182.2395
• Mol File: 78725-90-3.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 264°C at 760 mmHg
• Flash Point: 118.5°C
• Density: 1.16g/cm³
• Vapor Pressure: 0.00994mmHg at 25°C
• Refractive Index: 1.556
• CAS DataBase Reference: O-ethyl S-phenyl carbonothioate(CAS DataBase Reference)
• NIST Chemistry Reference: O-ethyl S-phenyl carbonothioate(78725-90-3)
• EPA Substance Registry System: O-ethyl S-phenyl carbonothioate(78725-90-3)

Safety Data

• Hazardous Substances Data: 78725-90-3(Hazardous Substances Data)

Upstream product

• 57361-48-5 ethoxycarbonyl isothiocyanate 
• 930-69-8 sodium thiophenolate 
• 882-33-7 diphenyldisulfane 
• 4114-31-2 ethylhydrazine carboxylate 
• 64-17-5 ethanol 
• 32315-10-9 bis(trichloromethyl) carbonate 
• 108-98-5 thiophenol 
• 934-87-2 S-phenyl thioacetate 
• 201230-82-2 carbon monoxide 
• 130755-47-4 (dichlorofluoromethyl)(phenyl)sulfide 
• 541-41-3 chloroformic acid ethyl ester 
• 53074-84-3 O-ethyl S-phenyl monothiooxalate 
• 76200-57-2 1-(trimethylsilyloxy)propyl phenyl sulfide 
• 3111-52-2 potassium thiophenolate 

Downstream Products

• 64-17-5 ethanol 
• 124-38-9 carbon dioxide 
• 4500-58-7 2-ethylthiophenol 
• 108-98-5 thiophenol 
• 51-79-6 urethane 
• 98-11-3 benzenesulfonic acid 
• 17101-98-3 (4-methyl-benzyl)carbamic acid ethyl ester 
• 444901-21-7 ethyl 3-chlorobenzylcarbamate 
• 2621-78-5 ethyl N-benzylcarbamate 
• 35573-36-5 N-(4-methoxyphenylmethyl)carbamic acid ethyl ester 
• 51172-60-2 ethyl (4-chlorobenzyl)carbamate 
• 71-43-2 benzene 

Relevant articles and documents

Cu-Catalyzed Oxidative Thioesterification of Aroylhydrazides with Disulfides

An alternative thioesterification reaction via copper-catalyzed oxidative coupling of readily available aroylhydrazides with disulfides is developed, in which oxidative expulsion of N2 overcomes the activation barrier between the carboxylic acid derivativ

A new method for synthesis of S-aryl-O-alkyl thiolcarbonates: Selenium-catalyzed reaction of alcohols with carbon monoxide and diaryl disulfides

A unique catalytic ability of selenium has been developed. When alcohols were allowed to react with diaryl disulfides in the presence of a catalytic amount of selenium under a pressurized carbon monoxide, S-aryl-O-alkyl thiolcarbonates were obtained in moderate to good yields.

Kinetics and mechanism of the aminolysis of O-ethyl S-aryl thiocarbonates in acetonitrile

The Kinetics and mechanism of the reactions of O-ethyl S-(Z)aryl thiocarbonates with (X)benzylamines in acetonitrile at 45.0 °C are studied. Relatively small values of βx (βnuc) = 0.6 to approximately 0.8 and βz (βlg) = -0.5 to approximately -0.7 together with a negative cross-interaction constant ρxz (= -0.47) and failure of the reactivity-selectivity principle (RSP) are interpreted to indicate a concerted mechanism. The normal kinetic isotope effects (kH/kD = 1.3 to approximately 1.8) involving deuterated benzylamine nucleophiles suggest a hydrogen-bonded, four-center-type transition state.