79121-34-9

Basic information

• Product Name: Ethanone, 1-cyclohexyl-2-(phenylthio)-
• CAS NO: 79121-34-9
• Molecular Formula: C14H18OS
• Molecular Weight: 234.362
• Mol File: 79121-34-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Ethanone, 1-cyclohexyl-2-(phenylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-cyclohexyl-2-(phenylthio)-(79121-34-9)
• EPA Substance Registry System: Ethanone, 1-cyclohexyl-2-(phenylthio)-(79121-34-9)

Safety Data

• Hazardous Substances Data: 79121-34-9(Hazardous Substances Data)

Upstream product

• 4630-82-4 methyl cyclohexylcarboxylate 
• 66080-23-7 4,4,5,5-tetramethyl-2-((phenylsulfanyl)methyl)-1,3,2-dioxaborolane 
• 56077-28-2 Bromomethyl cyclohexyl ketone 
• 108-98-5 thiophenol 
• 67975-88-6 (phenylthio)methaneboronic acid 
• 13307-75-0 (phenylthio)methyllithium 
• 80783-98-8 N-methoxy-N-methylcyclohexanecarboxamide 
• 111731-05-6 1,1-bis(phenylthio)-2-cyclohexyl-2-ethanone 

Downstream Products

• 206278-56-0 (Z)-1-Cyclohexyl-2-phenylsulfanyl-hept-2-en-1-one 
• 94719-38-7 1-Cyclohexyl-2-phenylsulfanyl-heptan-1-one 

Relevant articles and documents

Sulfone Group as a Versatile and Removable Directing Group for Asymmetric Transfer Hydrogenation of Ketones

The sulfone functional group has a strong capacity to direct the asymmetric transfer hydrogenation (ATH) of ketones in the presence of [(arene)Ru(TsDPEN)H] complexes by adopting a position distal to the η6-arene ring. This preference provides a

Enantioselective synthesis of α-hydroxy thioesters via oxazaborolidine- mediated reduction of α-phenylthio enones

α-Phenylthio-α,β-alkenones (2), readily available by Pd(II)-catalysed coupling of (E)-1 phenylthio-1-tributylstannylhex-1-ene with the corresponding acid chlorides have been treated with borane in the presence of phenylglycine- or proline-derived oxazaborolidines to afford 2-phenylthio-2- alken-1-ols (3) with good to excellent enantioselectivities. Ozonolysis of 3 provides a new and efficient route to chiral α-hydroxy thioesters 4.