791612-76-5Relevant articles and documents
Stereocontrolled construction of either stereoisomer of 12-oxatricyclo[6.3.1.02,7]dodecanes using prins-pinacol reactions
Overman, Larry E.,Velthuisen, Emile J.
, p. 3853 - 3856 (2004)
12-Oxatricyclo[6.3.1.02,7]dodecanes can be efficiently synthesized in a stereoselective manner by Prins-pinacol reactions. By biasing the transition state of the Prins cyclization, it is possible to access either stereoisomer of this oxatricyclic ring system.