79177-89-2

Basic information

• Product Name: mer-[IrCl₃[PMe(CH₂Ph)2]3]
• CAS NO: 79177-89-2
• Molecular Weight: 983.4
• Mol File: 79177-89-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: mer-[IrCl₃[PMe(CH₂Ph)2]3](CAS DataBase Reference)
• NIST Chemistry Reference: mer-[IrCl₃[PMe(CH₂Ph)2]3](79177-89-2)
• EPA Substance Registry System: mer-[IrCl₃[PMe(CH₂Ph)2]3](79177-89-2)

Safety Data

• Hazardous Substances Data: 79177-89-2(Hazardous Substances Data)

Upstream product

• 10025-83-9 iridium (III) chloride 
• 61236-06-4 dibenzyl methylphosphine 

Relevant articles and documents

Transition Metal-carbon Bonds. Part 50. Conversion of mer- (R=Me OR Ph) to (Three-membered Ring) by the Action of Base: Crystal Structure of

Treatment of complexes of type mer- (R = Ph or Me) with strong bases, LiNPrt2, LiBun, or Li(CH2)5Li, gives the three-membered ring metallocycles , (4a) and (4b), in high yield.Treatment of mer- with LiNPri2 probably gives a mixture of geometrical and optical isomers , (6) and (7).These three-membered ring metallocycles with hydrogen chloride are quantitatively converted back to mer- The reaction of complex (4a) with X2 (X = Cl, Br, and I) gives (8a), (8b), and (8c) respectively.The mer isomer (8a) on irradiation with visible light gives the corresponding fac isomer (9).I.r., 1H, 13C, and 31P n.m.r. data are given and discussed.The crystal structure of (4a) has been determined and refined to R 0.047.Cell dimensions are a = 11.619(2), b = 9.248(2), c = 25.498(5) Angstroem, and Z = 4, space group P212121.