79233-13-9

Basic information

• Product Name: 1,4-dimethoxy-2-(3-methylbut-2-en-1-yl)benzene
• CAS NO: 79233-13-9
• Molecular Formula: C₁₃H₁₈O₂
• Molecular Weight: 206.2808
• Mol File: 79233-13-9.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 289.9°C at 760 mmHg
• Flash Point: 105.2°C
• Density: 0.967g/cm³
• Vapor Pressure: 0.00372mmHg at 25°C
• Refractive Index: 1.502
• CAS DataBase Reference: 1,4-dimethoxy-2-(3-methylbut-2-en-1-yl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4-dimethoxy-2-(3-methylbut-2-en-1-yl)benzene(79233-13-9)
• EPA Substance Registry System: 1,4-dimethoxy-2-(3-methylbut-2-en-1-yl)benzene(79233-13-9)

Safety Data

• Hazardous Substances Data: 79233-13-9(Hazardous Substances Data)

Usage

Structure

Benzene derivative with two methoxy groups and a 3-methylbut-2-en-1-yl side chain

Usage

Primarily used as a research chemical

Common Applications

Not commonly found in consumer products

Similar Compounds

Used as fragrances or flavoring agents

Industry Documentation

Exact uses and applications are not well-documented

Precautions

Should be taken when handling in the laboratory due to intricate structure and potential reactivity

Upstream product

• 25974-58-7 4-methoxy-2-(3-methylbut-2-enyl)phenol 
• 74-88-4 methyl iodide 
• 150-76-5 4-methoxy-phenol 
• 115-18-4 2-methyl-3-buten-2-ol 
• 83036-58-2 prenyl diisopropyl phosphate 
• 150-78-7 1,4-dimethoxybezene 
• 870-63-3 prenyl bromide 
• 18293-99-7 Prenyltrimethylsilane 

Downstream Products

• 94828-08-7 2-(3-Chloro-3-methyl-2-phenylsulfanyl-butyl)-1,4-dimethoxy-benzene 
• 94828-28-1 2-(4'-hydroxy-3'-methyl-2'-(E)-butenyl)-1,4-dimethoxybenzene 
• 94828-21-4 2-(3'-methyl-2'-phenylthio-3'-butenyl)-1,4-dimethoxybenzene 

Relevant articles and documents

Electrophilic allylation of arenes with in situ generated allyltriarylbismuthonium compound: The Bismuth-mediated polarity inversion of allylsilanes

Reaction of triarylbismuth difluorides 1 with allyltrimethylsilane 2 in CH2Cl2 in the presence of BF3·OEt2 at low temperature generates allyltriarylbismuthonium compound 3 as a pale yellow solution, in which aromatic hydrocarbons and ethers, triphenylphosphine, dimethyl sulfide, p-toluenesulfinate, and thiophenol are all readily allylated to afford the corresponding allyl derivatives in moderate to good yields.

AN EFFICIENT REGIO- AND STEREOSPECIFIC ALKENYLATION OF PHENOLIC ETHERS BY PRENYL AND GERANYL DIISOPROPYL PHOSPHATES

Prenyl and geranyl diisopropyl phosphates readily alkenylate a variety of phenolic ethers regio- and stereospecifically without any appreciable side reactions.