792943-91-0

Basic information

• Product Name: ba-L-Mannopyranoside, methyl 6-deoxy-4-O-methyl-2,3-O-methylene- (9CI)
• Synonyms: bta-L-Mannopyranoside,methyl6-deoxy-4-O-methyl-2,3-O-methylene-(9CI);ba-L-Mannopyranoside, methyl 6-deoxy-4-O-methyl-2,3-O-methylene- (9CI)
• CAS NO: 792943-91-0
• Molecular Formula: C9H16O5
• Molecular Weight: 204.22034
• Product Categories: METHYL
• Mol File: 792943-91-0.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: ba-L-Mannopyranoside, methyl 6-deoxy-4-O-methyl-2,3-O-methylene- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: ba-L-Mannopyranoside, methyl 6-deoxy-4-O-methyl-2,3-O-methylene- (9CI)(792943-91-0)
• EPA Substance Registry System: ba-L-Mannopyranoside, methyl 6-deoxy-4-O-methyl-2,3-O-methylene- (9CI)(792943-91-0)

Safety Data

• Hazardous Substances Data: 792943-91-0(Hazardous Substances Data)

Upstream product

• 53577-83-6 methyl endo-2,3-O-benzylidene-4-O-methyl-α-L-rhamnopyranoside 
• 115262-02-7 methyl 2-O-benzyl-3,4-di-O-methyl-α-L-rhamnopyranoside 
• 35939-76-5 methyl 3,4-di-O-methyl-α-L-rhamnopyranoside 
• 3240-34-4 [bis(acetoxy)iodo]benzene 
• 792943-67-0 Methyl-3,4-di-O-methyl-β-L-rhamnopyranosid 

Relevant articles and documents

Selective cleavage of methoxy protecting groups in carbohydrates

The selective cleavage of methoxy protecting groups next to hydroxy groups is achieved using a radical hydrogen abstraction reaction as the key step. Under the reaction conditions, the hydroxy group generates an alkoxyl radical that reacts with the sterically accessible adjacent methoxy group, which is transformed into an acetal. In the second step, the acetals are hydrolyzed to give alcohols or diols. A one-pot hydrogen abstraction-hydrolysis procedure was also developed. Good yields were usually achieved, and the mild conditions of this methodology were compatible with different functional groups and sensitive substrates such as carbohydrates.