79328-17-9

Basic information

• Product Name: 3-dimethylphenylsilyl-1-phenyl-1-propene
• Synonyms: 3-dimethylphenylsilyl-1-phenyl-1-propene
• CAS NO: 79328-17-9
• Molecular Weight: 252.431
• Mol File: 79328-17-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 3-dimethylphenylsilyl-1-phenyl-1-propene(CAS DataBase Reference)
• NIST Chemistry Reference: 3-dimethylphenylsilyl-1-phenyl-1-propene(79328-17-9)
• EPA Substance Registry System: 3-dimethylphenylsilyl-1-phenyl-1-propene(79328-17-9)

Safety Data

• Hazardous Substances Data: 79328-17-9(Hazardous Substances Data)

Upstream product

• 185990-03-8 dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane 
• 444575-79-5 carbonic acid 1,1-dimethylethyl 1-phenyl-2-propenyl ester 
• 124517-47-1 cinnamyl tert-butyl carbonate 
• 100-52-7 benzaldehyde 
• 1234935-78-4 (dimethyl(phenyl)silyl)zinc chloride 
• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 
• 4393-06-0 1-Phenyl-2-propen-1-ol 
• 2327-99-3 1-phenylpropadiene 
• 768-33-2 phenyldimethylsilyl chloride 
• 2687-12-9 cinnamyl chloride 

Downstream Products

• 81194-40-3 3,4,4-triphenyl-1-butene 

Relevant articles and documents

Palladium-Catalyzed Benzylic Silylation of Diarylmethyl Carbonates with Silylboranes under Base-Free Conditions

A palladium-catalyzed benzylic silylation of diarylmethyl carbonates with silylboranes has been developed. The reaction proceeds smoothly even under external base-free conditions, and the corresponding benzylic silanes are formed in good to high yields. The obtained benzyl silane derivatives can work as the benzylic nucleophiles by the action of a suitable fluoride source and react with some carbon electrophiles to deliver the corresponding benzylic C?C cross-coupled products. Additionally, while still preliminary, the allylic silylation of the isoelectronic allylic carbonates is also achieved.

Cu(I)-NHC-Catalyzed Silylation of Allenes: Diastereoselective Three-Component Coupling with Aldehydes

Copper-catalyzed silylation of aryl allenes using a silylborane reagent affords vinyl silane building blocks with high efficiency. The use of a seven-membered NHC ligand proved crucial for high regioselectivity. The catalytically generated allylcoppper intermediates were intercepted by aldehydes in a diastereoselective three-component coupling to furnish homoallylic alcohols. Seven′s up! The use of a seven-membered N-heterocyclic carbene (NHC) ligand proved crucial in exerting high regiocontrol during the development of the first copper-catalyzed silylation of allenes using a commercial silylborane reagent. The process affords privileged vinyl silane building blocks with high efficiency. Allylcopper intermediates can be intercepted by aldehydes in a highly diastereoselective three-component coupling to furnish homoallylic alcohols.