79386-43-9

Basic information

• Product Name: diphenyl 2,3,4,6-tetra-O-benzyl-α-D-glucosyl phosphate
• Synonyms: diphenyl 2,3,4,6-tetra-O-benzyl-α-D-glucosyl phosphate
• CAS NO: 79386-43-9
• Molecular Weight: 772.832
• Mol File: 79386-43-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: diphenyl 2,3,4,6-tetra-O-benzyl-α-D-glucosyl phosphate(CAS DataBase Reference)
• NIST Chemistry Reference: diphenyl 2,3,4,6-tetra-O-benzyl-α-D-glucosyl phosphate(79386-43-9)
• EPA Substance Registry System: diphenyl 2,3,4,6-tetra-O-benzyl-α-D-glucosyl phosphate(79386-43-9)

Safety Data

• Hazardous Substances Data: 79386-43-9(Hazardous Substances Data)

Upstream product

• 4291-69-4 2,3,4,6-Tetra-O-benzyl-D-glucopyranose 
• 2524-64-3 chlorophosphoric acid diphenyl ester 
• 838-85-7 diphenyl hydrogen phosphate 
• 74808-09-6 2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl trichloroacetimidate 

Downstream Products

• 151909-91-0 isopropyl 2,3,4,6-tetra-O-benzyl-D-glucopyranoside 
• 55628-54-1 3,4,6-tri-O-benzyl-D-glucal 
• 56632-57-6 methyl O-2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl-(1->6)-2,3,4-tri-O-benzyll-α-D-glucopyranoside 
• 53008-62-1 2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl iodide 
• 77117-44-3 methyl 2,3,6-tri-O-benzyl-4-O-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-α-D-glucopyranoside 
• 64694-18-4 methyl 2,3,6-tri-O-benzyl-4-O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-α-D-glucopyranoside 
• 55094-26-3 methyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl-(1-6)-2,3,4-tri-O-benzyl-α-D-glucopyranoside 
• 77667-81-3 4-(2′-naphthyl) 2,3,4,6-tetra-O-benzyl-α-D-glucopyranoside 
• 82659-52-7 1-(2,3,4,6-O-tetrabenzyl-α-D-glucopyranosyl)-2-propene 
• 95084-06-3 2-(2,3,4,6-Tetra-O-benzyl-α,β-D-glucopyranosyl)-1-cyclopentanon 
• 350480-15-8 2-(2',3',4',6'-tetra-O-benzyl-β-D-glucopyranosyl)-3,4,5-trimethoxyphen-1-ol 
• 64842-82-6 2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl-(1->6)-[1:2,3:4]-di-O-isopropylidene-α-D-galactopyranoside 
• 41671-29-8 2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl-(1->6)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranoside 
• 173395-55-6 (3aR,5R,5aS,8aS,8bR)-2,2,7,7-tetramethyl-5-((((3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-yl)oxy)methyl)tetrahydro-3aH-bis[1,3]dioxolo[4,5-b:4',5'-d]pyran 

Relevant articles and documents

Synthesis and Transformation of Sugar Phosphates

Sugar diphenyl phosphates can be conveniently prepared by the treatment of monosaccharides with diphenylphosphorochloridate under phase-transfer conditions. Key words: synthesis, phosphorylation, sugar phosphates, catalytic two-phase system, thiosugars

Glycosyl Imidates, 10. - Glycosyl Phosphates from Glycosyl Trichloroacetimidates

The glycosyl trichloroacetimidates 1-α,β, 8-α, 11-α, 13-α, 15-α, and 17-α directly transfer the glycosyl moiety to phosphoric acid mono- and diesters.The acidity of the phosphoric acid derivatives used was sufficient for the activation of the trichloroacetimidates, therefore an additional acidic catalyst was not required.From the β-imidate 1-β α-glycosyl phosphate and from the α-imidates preferentially β-glycosyl phosphates were obtained.Reaction of dibenzyl phosphate (2a) and cetyl phosphate (2c) with 1-α demonstrated that β/α-anomerization iscatalyzed by traces of acid.The glycosyl phosphates 3a-α, 3a-β - 3c-β, 3f-α, 9a-β, and 9c-β were partly or totally deprotected.The structures of the synthezised compounds were assigned by 1H NMR spectroscopy and by comparison with literature data.