794512-47-3Relevant articles and documents
General silaindene synthesis based on intramolecular reductive cyclization toward new fluorescent silicon-containing π-electron materials
Xu, Caihong,Wakamiya, Atsushi,Yamaguchi, Shigehiro
, p. 3707 - 3710 (2004)
(Chemical Equation Presented) The reaction of (o-silylphenyl)acetylene derivatives with lithium naphthalenide undergoes intramolecular reductive cyclization to produce various silaindene derivatives. On the basis of this methodology, a series of silaindene-containing π-electron systems are synthesized that show intense blue to greenish-blue fluorescence.
Gold-catalysed alkenyl- and arylsilylation reactions forming 1-silaindenes
Matsuda, Takanori,Yamaguchi, Yoshiyuki,Shigeno, Masanori,Sato, Shinya,Murakami, Masahiro
, p. 8697 - 8699 (2011/09/15)
In the presence of gold(i)-phosphine catalysts, alkenyl- and arylsilanes undergo intramolecular cyclisation reactions onto appendant alkyne moieties to afford 1-silaindene derivatives. The reaction pathways vary depending on the substituent on silicon. The Royal Society of Chemistry 2011.
Synthesis of benzo[b]siloles via KH-promoted cyclization of (2-Alkynylphenyl)silanes
Llies, Laurean,Tsuji, Hayato,Nakamura, Eiichi
supporting information; experimental part, p. 3966 - 3968 (2009/12/03)
(Figure Presented) (2-Alkynylphenyl)silanes undergo intramolecular cyclization in the presence of an excess or a subequimolar amount of potassium hydride to give a variety of new 2-substituted benzosiloles in good to excellent yields. Some of these compou
