79458-27-8Relevant articles and documents
Selective, cofactor-mediated catalytic oxidation of alkanethiols in a self-assembled cage host
Da Camara, Bryce,Dietz, Philip C.,Chalek, Kevin R.,Mueller, Leonard J.,Hooley, Richard J.
supporting information, p. 14263 - 14266 (2020/11/24)
A spacious Fe(ii)-iminopyridine self-assembled cage complex can catalyze the oxidative dimerization of alkanethiols, with air as stoichiometric oxidant. The reaction is aided by selective molecular recognition of the reactants, and the active catalyst is derived from the Fe(ii) centers that provide the structural vertices of the host. The host is even capable of size-selective oxidation and can discriminate between alkanethiols of identical reactivity, based solely on size. This journal is
Oxidative transformation of thiols to disulfides promoted by activated carbon-air system
Hayashi, Masahiko,Okunaga, Ken-Ichi,Nishida, Shunsuke,Kawamura, Kenjiro,Eda, Kazuo
supporting information; experimental part, p. 6734 - 6736 (2011/02/25)
Efficient oxidative transformation of thiols to disulfides took place in the presence of activated carbon under an oxygen (or air) atmosphere. The present oxidation method is available not only for a variety of thiols such as simple aromatic and aliphatic thiols but also for 3,4-dihydropyrimidin-2(1H)- thiones and N-Boc-l-cysteine.
Method for preparing aromatic diphenyl thioethers
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, (2008/06/13)
The invention concerns a method for preparing aromatic diphenyl thioethers. More particularly the invention concerns the preparation of 4-chloro-4′-thiomethyldiphenylether. The inventive method for preparing an aromatic diphenyl thioether is characterised in that it consists in reacting in an aqueous medium a diazonium salt of an aromatic diphenyl compound with a disulphide sulphur compound, in the presence of an efficient amount of a coupling catalyst.
