79493-16-6Relevant articles and documents
SYNTHESE D'ANALOGUES DE DERIVES DIOXAPROSTANOIEQUES A PARTIR DU D ET DU L-XYLOSE
Castellanos, L.,Gateau-Olesker, A.,Panne-Jacolot, F.,Cleophax, J.,Gero, S.D.
, p. 1691 - 1696 (2007/10/02)
Epoxides 7,8 and 9 have been prepared from D and L-xylose, and used for the synthesis of a precursor of ent-(11-oxa)PG 19 and of 9,13- and 7,11-dioxaprostanoiec acids 28 and 31.The site of the opening of the epoxides 7 and 9 with the carbanion derived from bis-(phenylthio)methane and with LiAlH4 is show by establishing structures of the products 11, 12, 20 et 21 by (13)CNMR spectroscopy.