79542-20-4

Basic information

• Product Name: Benzeneacetaldehyde, a-[(4-methylphenyl)methylene]-, (E)-
• CAS NO: 79542-20-4
• Molecular Formula: C16H14O
• Molecular Weight: 222.287
• Mol File: 79542-20-4.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzeneacetaldehyde, a-[(4-methylphenyl)methylene]-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzeneacetaldehyde, a-[(4-methylphenyl)methylene]-, (E)-(79542-20-4)
• EPA Substance Registry System: Benzeneacetaldehyde, a-[(4-methylphenyl)methylene]-, (E)-(79542-20-4)

Safety Data

• Hazardous Substances Data: 79542-20-4(Hazardous Substances Data)

Upstream product

• 624-31-7 4-tolyl iodide 
• 77134-00-0 3-(4-methylphenyl)prop-2-enyl acetate 
• 103-54-8 cinnamyl acetate 
• 134539-87-0 1-methyl-4-(3-phenyl-1-propen-1-yl)benzene 
• 134539-86-9 1-methyl-4-(3-phenyl-2-propen-1-yl)benzene 
• 106-38-7 para-bromotoluene 
• 34713-70-7 2-Phenylpropanal 
• 588-72-7 [(E)-2-bromoethenyl]benzene 
• 104-87-0 4-methyl-benzaldehyde 
• 122-78-1 phenylacetaldehyde 
• 7089-34-1 ((Z)-3-Dimethylamino-2-phenyl-allylidene)-dimethyl-ammonium; perchlorate 
• 4294-57-9 para-methylphenylmagnesium bromide 

Downstream Products

• 1589518-81-9 4-methyl-N-(6-methyl-2-phenyl-1H-inden-1-yl)benzenesulfonamide 
• 80815-78-7 Z,Z,E diphenyl-2,6 p-tolyl-1 hexatriene-1,3,5 

Relevant articles and documents

Oxygenation of Simple Olefins through Selective Allylic C?C Bond Cleavage: A Direct Approach to Cinnamyl Aldehydes

A novel metal-free allylic C?C σ-bond cleavage of simple olefins to give valuable cinnamyl aldehydes is reported. 1,2-Aryl or alkyl migration through allylic C?C bond cleavage occurs in this transformation, which is assisted by an alkyl azide reagent. This method enables O-atom incorporation into simple unfunctionalized olefins to construct cinnamyl aldehydes. The reaction features simple hydrocarbon substrates, metal-free conditions, and high regio- and stereoselectivity.

Assembly of indenamine derivatives through in situ formed N-sulfonyliminium ion initiated cyclization

An expedient route to structurally diverse indenamine derivatives through condensation of the readily accessible substituted cinnamylaldehydes and sulfonylamines under the catalysis of FeCl3 has been developed, featuring high efficiency in the generation of two bonds and one ring in a single-step and water as the only by-product. This journal is the Partner Organisations 2014.

Photocycloaddition selon un mode chez le E,Z,E diphenyl-2,6 p-tolyl-1 hexatriene-1,3,5

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