79721-96-3Relevant articles and documents
Hexagonal structural modification of [Rh(dicbp)2+Cl-]n and two-dimensional [Ir(dic)2+Cl-]n polymers
Efraty, Avi,Feinstein, Irene,Frolow, Felix
, p. 485 - 488 (2008/10/08)
The preparation and characterization of a hexagonal structural modification of [Rh(dicbp)2+Cl-]n (dicbp = 4,4′-diisocyanobiphenyl) is described: This stacked layer polymer contains an extensive network of columnar metal chains with intrachain Rh-Rh distances of 3.54 ?. The hexagonal polymer undergoes pressure-induced isomerization to the tetragonal structural modification. The preparation and characterization of a series of iridium polymers of the type [Ir(dic)2+Cl-]n (dic = diisocyanide) are also described. The new iridium polymer consists of two-dimensional layered structures.