79762-78-0

Basic information

• Product Name: ALPHA-BROMO-TERT-BUTYL ACRYLATE, 95%
• Synonyms: tert-butyl 2-bromoacrylate;α-bromo-tert-butyl acrylate;tert-Butyl 2-broMoacrylate 95%;tert-butyl 2-bromoprop-2-enoate
• CAS NO: 79762-78-0
• Molecular Formula: C₇H₁₁BrO₂
• Molecular Weight: 207.07
• Mol File: 79762-78-0.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 80-85 °C/35 mmHg(lit.)
• Flash Point: 88 °C
• Appearance: /
• Density: 1.277 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.482mmHg at 25°C
• Refractive Index: n20/D 1.458(lit.)
• Storage Temp.: ?20°C
• CAS DataBase Reference: ALPHA-BROMO-TERT-BUTYL ACRYLATE, 95%(CAS DataBase Reference)
• NIST Chemistry Reference: ALPHA-BROMO-TERT-BUTYL ACRYLATE, 95%(79762-78-0)
• EPA Substance Registry System: ALPHA-BROMO-TERT-BUTYL ACRYLATE, 95%(79762-78-0)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36
• WGK Germany: 3
• Hazardous Substances Data: 79762-78-0(Hazardous Substances Data)

Usage

General Description

Alpha-Bromo-tert-butyl acrylate, 95% is a chemical compound that is commonly used in the manufacturing of polymers and other industrial products. It is a colorless liquid with a distinct acrid odor and is highly flammable. ALPHA-BROMO-TERT-BUTYL ACRYLATE, 95% is also known for its ability to polymerize at elevated temperatures and is often used as a building block for various advanced materials. It is important to handle alpha-bromo-tert-butyl acrylate with caution, as it can be hazardous if not handled properly.

InChI:InChI=1/C7H11BrO2/c1-5(8)6(9)10-7(2,3)4/h1H2,2-4H3

Upstream product

• 1663-39-4 tert-Butyl acrylate 
• 138034-79-4 tert-butyl 2,3-dibromopropionate 

Downstream Products

• 1583281-43-9 C₃₈H₅₅NO₃Si 
• 1583281-41-7 C₄₀H₅₉NO₃Si 

Relevant articles and documents

How Reaction Conditions May Influence the Regioselectivity in the Synthesis of 2,3-Dihydro-1,4-benzoxathiine Derivatives

The exploration of different reaction conditions aiming to obtain both 2,3-dihydro-1,4-benzoxathiine-2-yl derivatives and 2,3-dihydro-1,4-benzoxathiine-3-yl ones is reported. The treatment of 1,2-mercaptophenol with an organic base and a specific 2-bromo acrylate results in a solvent- and substrate-dependent exclusive solvation of O- and S-anions, thus managing the regioselectivity.

Mechanism-based inactivation of coenzyme B12-dependent 2-methyleneglutarate mutase by (Z)-glutaconate and buta-1,3-diene-2,3- dicarboxylate

In the presence of holo 2-methyleneglutarate mutase, buta-1,3-diene-2,3- dicarboxylate and (Z)-glutaconate [(Z)-pent-2-ene-1,5-dicarboxylate], but not (E)-glutaconate, each induced homolysis of the Co-C bond of coenzyme B 12 to afford cob(II)alamin and the 5′-deoxyadenosyl radical. The latter probably added to the double bond in (Z)-glutaconate and one of the double bonds in buta-1,3-diene-2,3-dicarboxylate to afford a corresponding "radical adduct". The formation of new radicals and cob(II)alamin was diagnosed by UV/Visible and EPR spectroscopy. (Z)-Glutaconate rapidly inactivated the mutase with formation of aquocobalamin, which was possibly derived by electron transfer from cob(II)alamin to the radical adduct. In contrast, buta-1,3-diene-2,3-dicarboxylate was a much slower inactivator. In this case, the spectroscopic data revealed a relatively stable complex of the radical adduct with cob(II)alamin in the active site of the enzyme. Wiley-VCH Verlag GmbH & Co. KGaA, 2006.