79852-48-5

Basic information

• Product Name: Benzenemethanol, a-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]-
• CAS NO: 79852-48-5
• Molecular Formula: C10H7F7O
• Molecular Weight: 276.154
• Mol File: 79852-48-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, a-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, a-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]-(79852-48-5)
• EPA Substance Registry System: Benzenemethanol, a-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]-(79852-48-5)

Safety Data

• Hazardous Substances Data: 79852-48-5(Hazardous Substances Data)

Upstream product

• 677-69-0 perfluoroisopropyl iodide 
• 100-52-7 benzaldehyde 

Relevant articles and documents

Ultrasound-Promoted Selective Perfluoroalkylation on the Desired Position of Organic Molecules

Perfluoroalkylzinc iodides or bromides wich were prepared from perfluoroalkyl iodides or bromides and zinc powder in N,N-dimethylformamide or tetrahydrofuran with ultrasonic irradiation were found to behave as potential perfluoroalkylating reagents for the preparation of a wide variety of perfluoroalkylated compounds.Especially, the ultrasound-promoted asymmetric induction with perfluoroalkyl group on the asymmetrical carbon was achieved by the reaction of perfluoroalkyl halides with optically active enamines in the presence of zinc powder and a catalytic amount of dichlorobis(?-cyclopentadienyl)titanium.

PERFLUOROALKYLTIN(IV) HALIDES: A NOVEL PERFLUOROALKYLATING AGENT FOR CARBONYL COMPOUNDS

Perfluoroalkyltin(IV) halides (RfSnX2I) were prepared in situ by the oxidative addition of perfluoroalkyl iodides to tin(II) halide in N,N-dimethylformamide.Aldehydes and ketones readily reacted with RfSnCl2I giving perfluoroalkylcarbinols in the N,N-dimethylformamide-pyridine system.RfSnF2I, however, did not undergo the reactions with these carbonyl compounds.