798548-25-1

Basic information

• Product Name: Phosphine, [2-[[4'-[2-(diphenylphosphino)ethoxy][1,1'-biphenyl]-4-yl]thio]ethyl]diphen yl-
• CAS NO: 798548-25-1
• Molecular Formula: C40H36OP2S
• Molecular Weight: 626.739
• Mol File: 798548-25-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Phosphine, [2-[[4'-[2-(diphenylphosphino)ethoxy][1,1'-biphenyl]-4-yl]thio]ethyl]diphen yl-(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphine, [2-[[4'-[2-(diphenylphosphino)ethoxy][1,1'-biphenyl]-4-yl]thio]ethyl]diphen yl-(798548-25-1)
• EPA Substance Registry System: Phosphine, [2-[[4'-[2-(diphenylphosphino)ethoxy][1,1'-biphenyl]-4-yl]thio]ethyl]diphen yl-(798548-25-1)

Safety Data

• Hazardous Substances Data: 798548-25-1(Hazardous Substances Data)

Upstream product

• 252044-23-8 4-(2-chloro-ethoxy)-phenylboronic acid 
• 16181-14-9 1-bromo-4-(2-chloro-ethylsulfanyl)-benzene 
• 15475-27-1 potassium diphenylphosphine 
• 798548-42-2 4-(2-chloro-ethoxy)-4'-(2-chloro-ethylsulfanyl)-biphenyl 

Relevant articles and documents

Halide-induced supramolecular ligand rearrangement

A novel reaction involving the halide-induced rearrangement of ligands within supramolecular Rh(I) complexes containing hemilabile ligands is presented. Three analogous bis- and trishemilabile ligands have been synthesized to construct bi- and trimetallic Rh(I) macrocyclic complexes. An intentionally added halide source results in the formal rotation of only one hemilabile ligand along the axis that is perpendicular to the plane defined by the aryl backbone of the hemilabile ligands. X-ray structures, as determined by X-ray crystallography, of key intermediates and products are presented. Copyright