798568-63-5

Basic information

• Product Name: 2-cyclohexylidene-1-methoxy-3-methyl-1-trimethylsilyloxycyclopropane
• Synonyms: 2-cyclohexylidene-1-methoxy-3-methyl-1-trimethylsilyloxycyclopropane
• CAS NO: 798568-63-5
• Molecular Weight: 254.445
• Mol File: 798568-63-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-cyclohexylidene-1-methoxy-3-methyl-1-trimethylsilyloxycyclopropane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-cyclohexylidene-1-methoxy-3-methyl-1-trimethylsilyloxycyclopropane(798568-63-5)
• EPA Substance Registry System: 2-cyclohexylidene-1-methoxy-3-methyl-1-trimethylsilyloxycyclopropane(798568-63-5)

Safety Data

• Hazardous Substances Data: 798568-63-5(Hazardous Substances Data)

Upstream product

• 34880-70-1 [1-methoxyprop-1-enyloxy]trimethylsilane 

Relevant articles and documents

Regioselective ring opening of alkylidenecyclopropanone silyl acetals

Alkylidenecyclopropanone silyl acetals have been prepared from an iodonium salt via an alkylidenecarbene. Three different C-C bonds of the cyclopropane ring can be selectively cleaved with appropriate reagents. Alkylidenecyclopropanone silyl acetals are readily available from the reaction of an alkylidenemethyliodonium salt and ketene silyl acetals in the presence of triethylamine. The three different C-C bonds of the cyclopropane ring can be selectively cleaved with HCl, Lewis acid, or fluoride. The alkylideneallyl cation formed via the cleavage of C2-C3 bond with Lewis acids shows further selectivity in reacting with a nucleophile.