799-35-9Relevant articles and documents
Silane bridging luminescent material, preparation method and application thereof, and color developing agent
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Paragraph 0078; 0082-0084, (2020/07/13)
The invention relates to the technical field of detection, and discloses a silane bridging luminescent material, a preparation method and an application thereof, and a color developing agent, the silane bridging luminescent material has a structure repres
Conductive molecular silicon
Klausen, Rebekka S.,Widawsky, Jonathan R.,Steigerwald, Michael L.,Venkataraman, Latha,Nuckolls, Colin
supporting information; experimental part, p. 4541 - 4544 (2012/04/23)
Bulk silicon, the bedrock of information technology, consists of the deceptively simple electronic structure of just Si-Si σ bonds. Diamond has the same lattice structure as silicon, yet the two materials have dramatically different electronic properties. Here we report the specific synthesis and electrical characterization of a class of molecules, oligosilanes, that contain strongly interacting Si-Si σ bonds, the essential components of the bulk semiconductor. We used the scanning tunneling microscope-based break-junction technique to compare the single-molecule conductance of these oligosilanes to those of alkanes. We found that the molecular conductance decreases exponentially with increasing chain length with a decay constant β = 0.27 ± 0.01 A-1, comparable to that of a conjugated chain of C = C π bonds. This result demonstrates the profound implications of σ conjugation for the conductivity of silicon.
Decomposition of bis( silyldiazomethyl) polysilanes: formation of polysilabicyclo(l.m.n)alkane derivatives
Ando, Wataru,Sugiyama, Mitsuru,Suzuki, Tomohisa,Kato, Chikako,Arakawa, Yusuke,Kabe, Yoshio
, p. 99 - 112 (2007/10/02)
The photolysis of bis(trimethylsilyldiazomethyl)disilane (4a) in tert-butyl alcohol provided the tert-butyl alcohol adducts S, 6, 7, 8 and 9.The structures of these products revealed the stepwise formation of asymmetric silenes as intermediates.Gas-phase