799261-87-3

Basic information

• Product Name: (1S,2S)-1,2-N,N'-bis(p-toluenesulfonylamino)-1,2-di-tert-butylethane
• Synonyms: (1S,2S)-1,2-N,N'-bis(p-toluenesulfonylamino)-1,2-di-tert-butylethane
• CAS NO: 799261-87-3
• Molecular Weight: 480.693
• Mol File: 799261-87-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (1S,2S)-1,2-N,N'-bis(p-toluenesulfonylamino)-1,2-di-tert-butylethane(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,2S)-1,2-N,N'-bis(p-toluenesulfonylamino)-1,2-di-tert-butylethane(799261-87-3)
• EPA Substance Registry System: (1S,2S)-1,2-N,N'-bis(p-toluenesulfonylamino)-1,2-di-tert-butylethane(799261-87-3)

Safety Data

• Hazardous Substances Data: 799261-87-3(Hazardous Substances Data)

Upstream product

• 799261-61-3 (4S,5S)-4-tert-Butyl-5-methoxy-1-((1S,2R,4R)-2-methoxy-7,7-dimethyl-bicyclo[2.2.1]heptane-1-carbonyl)-3-(toluene-4-sulfonyl)-imidazolidin-2-one 
• 98-59-9 p-toluenesulfonyl chloride 
• 171357-22-5 (S,S)-1,2-di-tert-butylethane-1,2-diamine 
• 799261-59-9 (4S,5S)-4-tert-Butyl-5-methoxy-1-((1S,2R,4R)-2-methoxy-7,7-dimethyl-bicyclo[2.2.1]heptane-1-carbonyl)-imidazolidin-2-one 
• 799261-65-7 (4S,5S)-trans-1-p-tolylsulfonyl-4,5-di-tert-butyl-2-imidazolidinone 
• 799261-63-5 (4S,5S)-5-tert-Butyl-4-methoxy-1-(toluene-4-sulfonyl)-imidazolidin-2-one 

Relevant articles and documents

Chiral bis(N-sulfonylamino)phosphine- and TADDOL-phosphite-oxazoline ligands: Synthesis and application in asymmetric catalysis

A series of N,P-ligands has been prepared, containing a chiral oxazoline ring and as a second chiral unit a bis(N-sulfonylamino)phosphine group embedded in a diazaphospholidine ring or a cyclic phosphite group derived from TADDOL. These modular ligands are readily synthesized from chiral amino alcohols and chiral 1,2-diamines or TADDOLs. Palladium and iridium complexes derived from these ligands were found to be efficient catalysts for enantioselective allylic alkylation and olefin hydrogenation, respectively.