79950-49-5

Basic information

• Product Name: Phenol, 2-(1,1-dimethylethyl)-4-(2-propenyloxy)-
• CAS NO: 79950-49-5
• Molecular Formula: C13H18O2
• Molecular Weight: 206.285
• Mol File: 79950-49-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Phenol, 2-(1,1-dimethylethyl)-4-(2-propenyloxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Phenol, 2-(1,1-dimethylethyl)-4-(2-propenyloxy)-(79950-49-5)
• EPA Substance Registry System: Phenol, 2-(1,1-dimethylethyl)-4-(2-propenyloxy)-(79950-49-5)

Safety Data

• Hazardous Substances Data: 79950-49-5(Hazardous Substances Data)

Upstream product

• 106-95-6 allyl bromide 
• 1948-33-0 tert-butylhydroquinone 
• 107-05-1 3-chloroprop-1-ene 

Downstream Products

• 73685-60-6 2-(1,1-dimethylethyl)-5-(2-propenyl)-1,4-benzenediol 

Relevant articles and documents

Design and synthesis of new fluorinated ligands for the rhodium-catalyzed hydroformylation of alkenes in supercritical CO2 and fluorous solvents

Novel fluorous biphenols, 5,5′-[n-C4F9(CH2)3] 2-2,2′-biphenol and 5,5′-[n-C4F9(CH2)3O] 2-3,3′-di-tert-butyl-2,2′-biphenol, as well as enantiopure BINOLs, (S)-6,6′-[n-C4F9(CH2)3] 2-BINOL, (R)-6,6′-[n-C6F13(CH2)3} 2-BINOL, and (S)-6,6′-[n-C8F17(CH2)3] 2-BINOL, are synthesized. These compounds serve as key intermediates for the syntheses of a variety of new fluorous ligands for regioselective and enantioselective catalytic reactions. Novel fluorous [Rf(CH2)3]2-BINAPHOS ligands (Rf = n-C4F9, n-C6F13, and n-C8F17) are successfully synthesized. These new fluorous chiral ligands when used with a rhodium catalyst can achieve comparable or even higher regioselectivity and enantioselectivity in the asymmetric hydroformylation of styrene as compared to those by the Rh-BINAPHOS system.