799794-98-2Relevant articles and documents
Enantioselective total synthesis of (-)-Clavosolide A and B
Son, Jung Beom,Kim, Si Nae,Kim, Na Yeong,Hwang, Min-Ho,Lee, Wonsun,Lee, Duck Hyung
scheme or table, p. 653 - 663 (2010/08/19)
Enantioselective total synthesis of (-)-clavosolide A and B was reported in full including the synthesis of proposed structure of (-)-clavosoldie A (1), revised structure of (-)-clavosoldie A (5), and revised structure of (-)-clavosoldie B (6). The relative and absolute stereochemistries of the natural products were confirmed unambiguously by comparing the optical rotation values and 1H and 13C NMR spectra of them.
Studies towards the synthesis of the β-D-Xyl-(1→ 3)-L-ara disaccharide moiety of OSW-1 from Ornithogalum saundersiae
Suhr, Rene,Thiem, Joachim
, p. 261 - 276 (2007/10/03)
The OSW-1 disaccharide having 2-O-p-methoxybenzoyl-β-D-xylopyranosyl- (1 → 3)-L-arabinopyranoside structure was obtained as the benzylated 4-O-acetyl derivative 19. Also, the 4,2′-di-O-acetate 18 was synthesized by a short synthetic approach. The arabinos