80090-95-5Relevant articles and documents
Ir(iii)-Catalyzed direct C-H functionalization of N -phenylacetamide with α-diazo quinones: A novel strategy for producing 2-hydroxy-2′-amino-1,2′-biaryl scaffolds
Li, Xingjun,Wang, Jiang,Xie, Xiong,Dai, Wenhao,Han, Xu,Chen, Kaixian,Liu, Hong
supporting information, p. 3441 - 3444 (2020/03/30)
α-Diazo quinones were applied in an Ir(iii)-catalyzed direct C-H functionalization assisted by N-phenylacetamide for the construction of highly functionalized 2-hydroxy-2′-amino-1,1′-biaryl scaffolds in good to excellent yields. This strategy features ope
Nucleophilic Aromatic Substitution. Part XIV. Investigation of the Mechanism of Hydroxy-denitration of 4,2- and 2,4-Chloronitrobenzenediazonium Ions as a Function of pH
Pikulik, Ivan I.,Weber, Rudolf U.,Zollinger, Heinrich
, p. 1777 - 1789 (2007/10/02)
4,2-Chloronitrobenzenediazonium ions in aqueous buffer solutions between pH 2.9 and 7.9 do not hydrolyze by dediazoniation as previous authors have assumed, but by denitration.The isomeric 2,4-compound reacts by denitration (ca. 70percent) and dechlorinat