801237-26-3

Basic information

• Product Name: Acetic acid (2S,3S,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-2-((Z)-8-benzyloxy-1-vinyl-deca-4,9-dienyloxy)-tetrahydro-pyran-3-yl ester
• Synonyms: Acetic acid (2S,3S,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-2-((Z)-8-benzyloxy-1-vinyl-deca-4,9-dienyloxy)-tetrahydro-pyran-3-yl ester
• CAS NO: 801237-26-3
• Molecular Weight: 760.968
• Mol File: 801237-26-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Acetic acid (2S,3S,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-2-((Z)-8-benzyloxy-1-vinyl-deca-4,9-dienyloxy)-tetrahydro-pyran-3-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid (2S,3S,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-2-((Z)-8-benzyloxy-1-vinyl-deca-4,9-dienyloxy)-tetrahydro-pyran-3-yl ester(801237-26-3)
• EPA Substance Registry System: Acetic acid (2S,3S,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-2-((Z)-8-benzyloxy-1-vinyl-deca-4,9-dienyloxy)-tetrahydro-pyran-3-yl ester(801237-26-3)

Safety Data

• Hazardous Substances Data: 801237-26-3(Hazardous Substances Data)

Upstream product

• 444884-25-7 (Z)-1,6,11-dodecatriene-3,10-diol 
• 51097-60-0 (Z)-oct-4-enedial 
• 19740-90-0 (Z)-9-oxabicyclo[6.1.0]non-4-ene 
• 1552-12-1 1,5-cis,cis-cyclooctadiene 
• 108869-64-3 2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl trichloroacetimidate 

Downstream Products

• 801237-41-2 cyclopent-1-enyl 2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranoside 
• 68241-89-4 [(cyclopent-2-en-1-yloxy)methyl]benzene 
• 801237-28-5 Acetic acid (2S,3S,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-2-(cyclopent-2-enyloxy)-tetrahydro-pyran-3-yl ester 

Relevant articles and documents

A tandem ring-closing metathesis cleavable linker system for solid-phase oligosaccharide synthesis

A novel triene linker system, that can be cleaved by a tandem ring-closing metathesis (RCM) reaction, is presented. The tandem RCM cleavage, that regenerates the active ruthenium catalyst without the need of additives like ethylene, proceeded very clean and fast to liberate cyclopent-2-enyl mannosides from the solid support. A cyclopent-2-enyl mannoside was isomerized to the corresponding vinyl ether glycoside, which could be readily deprotected by iodine-mediated hydrolysis.