80137-71-9Relevant articles and documents
Aerobic alcohol oxidation coupled to palladium-catalyzed alkene hydroarylation with boronic esters
Iwai, Yasumasa,Gligorich, Keith M.,Sigman, Matthew S.
, p. 3219 - 3222 (2008/12/23)
(Chemical Equation Presented) An oxidation exercise: An aerobic alcohol oxidation coupled with a regioselective palladium-catalyzed reductive functionalization of styrenes and arylboronic esters has been developed (see scheme). The mechanism is thought to proceed by initial oxidation of the solvent to generate a PdII-hydride species, which subsequently reacts with the alkene and arylboronic ester to ultimately generate a new C-C bond.