80146-01-6

Basic information

• Product Name: pentamethylcyclopentadienyliridium(III) PMe₃ dihydride
• Synonyms: pentamethylcyclopentadienyliridium(III) PMe₃ dihydride
• CAS NO: 80146-01-6
• Molecular Weight: 405.543
• Mol File: 80146-01-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: pentamethylcyclopentadienyliridium(III) PMe₃ dihydride(CAS DataBase Reference)
• NIST Chemistry Reference: pentamethylcyclopentadienyliridium(III) PMe₃ dihydride(80146-01-6)
• EPA Substance Registry System: pentamethylcyclopentadienyliridium(III) PMe₃ dihydride(80146-01-6)

Safety Data

• Hazardous Substances Data: 80146-01-6(Hazardous Substances Data)

Upstream product

• 71-43-2 benzene 
• 110-82-7 cyclohexane 
• 165612-94-2 bis(pentafluorophenyl)borohydride 

Downstream Products

• 682748-88-5 (η5-C5Me5)(PMe3)Ir(H)[C(O)C(CH3)2(C6H5)] 
• 273750-33-7 IrHP(CH₃)3C₅(CH₃)5COC₆H₄CF₃ 
• 273750-35-9 IrHP(CH₃)3C₅(CH₃)5COC₆H₄OCH₃ 
• 344615-60-7 IrHP(CH₃)3C₅(CH₃)5COC₆H₄CH₃ 
• 273750-34-8 IrHP(CH₃)3C₅(CH₃)5COC₆H₄F 
• 273750-32-6 IrHP(CH₃)3C₅(CH₃)5COC₆H₄NO₂ 
• 327162-87-8 (C₅Me₅)(PMe₃)Ir(m-C₆H₄CH₃)(H) 
• 327162-84-5 (C₅Me₅)(PMe₃)Ir(o-C₆H₄CH₃)(H) 
• 327162-89-0 (C₅Me₅)(PMe₃)Ir(p-C₆H₄CH₃)(H) 
• 226882-84-4 (η(5)-C5Me5)(PMe3)Ir(BPh2)(H) 
• 226882-89-9 (η(5)-C5Me5)(PMe3)Ir(C6F5)(H) 
• 85453-01-6 (η5-C5Me5)Ir(PMe3)Br2 

Relevant articles and documents

Evidence for the intervention of different C-H activating intermediates in the irradiation of (η5-C5Me5)(PMe3) IrH2 and the reaction of (η5-C5Me5)(PMe3)Ir(H

Reaction of (η5-C5Me5)(PMe3)Ir(H)(X) (X = Cl, Br) with tert-butyllithium in hydrocarbon solvent results in dehydrohalogenation of the iridium center and subsequent C-H bond activation of solvent to give (η5