80253-77-6

Basic information

• Product Name: 2-cyano-5,6-dimethyl-7-(2,4-dinitroanilino)-heptatrienoic acid ethylester
• CAS NO: 80253-77-6
• Molecular Weight: 386.364
• Mol File: 80253-77-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-cyano-5,6-dimethyl-7-(2,4-dinitroanilino)-heptatrienoic acid ethylester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-cyano-5,6-dimethyl-7-(2,4-dinitroanilino)-heptatrienoic acid ethylester(80253-77-6)
• EPA Substance Registry System: 2-cyano-5,6-dimethyl-7-(2,4-dinitroanilino)-heptatrienoic acid ethylester(80253-77-6)

Safety Data

• Hazardous Substances Data: 80253-77-6(Hazardous Substances Data)

Upstream product

• 97-00-7 1-chloro-2,4-dinitro-benzene 
• 583-58-4 3,4-Lutidin 
• 80253-79-8 N-(2',4'-dinitrophenyl)-3,4-dimethylpyridinium chloride 
• 105-56-6 ethyl 2-cyanoacetate 

Relevant articles and documents

DERIVATIVES AND REACTIONS OF GLUTACONALDEHYDE-XIII. REGIOSPECIFIC RING OPENING OF 3-SUBSTITUTED PYRIDINES

A number of nucleophilic ring openings of 3-substituted pyridinium salts have been reinvestigated and summarized.The structure of the resulting stable glutaconaldehyde derivatives was investigated in detail by 1H NMR.It has been concluded that in general nucleophilic pyridinium ring openings are highly regiospecific.In each case investigated to date a single product was isolated, as a result of attack by the nucleophile at only one of the pyridine α-positions.With the OH ion as the only nucleophile, attack occurs at the pyridine C-2, while larger nucleophiles such as amines and carbanions attack at the pyridine C-6.This was found to be the case for a variety of 3-substituted pyridines such as 3-methyl-, 3-methoxy-, 3-cyano-, 3-chloro-pyridine.