80331-37-9

Basic information

• Product Name: 3-(3-Oxo-1,4-diphenyl-butyl)-benzaldehyde
• Synonyms: 3-(3-Oxo-1,4-diphenyl-butyl)-benzaldehyde
• CAS NO: 80331-37-9
• Molecular Weight: 328.411
• Mol File: 80331-37-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-(3-Oxo-1,4-diphenyl-butyl)-benzaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(3-Oxo-1,4-diphenyl-butyl)-benzaldehyde(80331-37-9)
• EPA Substance Registry System: 3-(3-Oxo-1,4-diphenyl-butyl)-benzaldehyde(80331-37-9)

Safety Data

• Hazardous Substances Data: 80331-37-9(Hazardous Substances Data)

Upstream product

• 5409-59-6 1,4-diphenyl-3-butene-2-one 
• 20883-40-3 3-formylphenylmercury chloride 

Relevant articles and documents

THE PALLADIUM-CATALYSED CONJUGATE ADDITION TYPE REACTION OF ARYLMERCURY COMPOUNDS WITH α,β-UNSATURATED KETONES IN A TWO-PHASE SYSTEM

Pd-catalysed reaction of arylmercury compounds with α,β-enones in an acidic two-phase system provides a mild and selective way to β-aryl ketones.The present conjugate addition type reaction may accomodate a wide variety of functional groups.Thus, aryl units containing electron-donating and electron-withdrawing substituents such as -Me, -Cl, -CHO, -COMe, -COOMe, -COOH, -OH, -OMe, -NHCOMe and NO2 were succesfully transfered to the β C atom of benzalacetone.A number of α,β-enones were also treated with 3-formylphenyl mercury chloride to give the corresponding β-(3-formylphenyl) derivatives.The main limitation seems to arise from steric hindrance in the starting α,β-enonic system.Substituents in the aryl moiety of the organomercury compounds were found to affect the transmetalation steps in the direction expected for a rate determining ?-complex formation.