80345-20-6

Basic information

• Product Name: 2-Propanone, 1-(1-hydroxycyclopropyl)- (9CI)
• Synonyms: 2-Propanone, 1-(1-hydroxycyclopropyl)- (9CI)
• CAS NO: 80345-20-6
• Molecular Formula: C₆H₁₀O₂
• Molecular Weight: 114.1424
• Product Categories: ACETYLGROUP
• Mol File: 80345-20-6.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-Propanone, 1-(1-hydroxycyclopropyl)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propanone, 1-(1-hydroxycyclopropyl)- (9CI)(80345-20-6)
• EPA Substance Registry System: 2-Propanone, 1-(1-hydroxycyclopropyl)- (9CI)(80345-20-6)

Safety Data

• Hazardous Substances Data: 80345-20-6(Hazardous Substances Data)

Upstream product

• 62266-37-9 cyclopropylidenepropanone 
• 241487-53-6 1-Acetonyl-1-hydroxycyclopropane ethylene acetal 

Downstream Products

• 241487-54-7 toluene-4-sulfonic acid 1-(2-oxo-propyl)-cyclopropyl ester 

Relevant articles and documents

A convenient method for the preparation of N-substituted 1-acetonylaminocyclopropanes from acetoacetic ester ethylene acetal

Reaction of 1-acetonyl-1-tosyloxycyclopropane with primary or secondary amines affords the corresponding 1-acetonyl-1-aminocyclopropanes in quantitative yields. The starting tosylate was prepared from acetoacetic ester ethylene acetal in three steps through its cyclopropanation with ethylmagnesium bromide in the presence of 0.2 equivalent of titanium (IV) isopropoxide, followed by deprotection of the carbonyl group and tosylation.

ADDITION REACTIONS TO α-CYCLOPROPYLIDENE KETONES AND ALDEHYDES.

α-Cyclopropylidene ketones show high reactivity towards 1,4-addition reactions.