80355-66-4

Basic information

• Product Name: Phenol, 4-methyl-2-(1,2,3,4-tetrahydro-1-naphthalenyl)-
• CAS NO: 80355-66-4
• Molecular Formula: C17H18O
• Molecular Weight: 238.329
• Mol File: 80355-66-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Phenol, 4-methyl-2-(1,2,3,4-tetrahydro-1-naphthalenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Phenol, 4-methyl-2-(1,2,3,4-tetrahydro-1-naphthalenyl)-(80355-66-4)
• EPA Substance Registry System: Phenol, 4-methyl-2-(1,2,3,4-tetrahydro-1-naphthalenyl)-(80355-66-4)

Safety Data

• Hazardous Substances Data: 80355-66-4(Hazardous Substances Data)

Upstream product

• 106-44-5 p-cresol 
• 529-33-9 1,2,3,4-Tetrahydro-1-naphthol 
• 612-17-9 1,4-dihydronaphthalene 
• 447-53-0 1,2-Dihydronaphthalene 

Relevant articles and documents

Secondary benzylation with benzyl alcohols catalyzed by a high-valent heterobimetallic Ir-Sn complex

(Chemical Equation Presented) A highly efficient secondary benzylation procedure has been demonstrated using a high-valent heterobimetallic complex [Ir2(COD)2(SnCls)2(Cl)2(μ-Cl) 2] 1 as the catalyst in 1,2-dichloroethane to afford the corresponding benzylated products in moderate to excellent yields. The reaction was performed not only with carbon nucleophiles (arenes and heteroarenes) but also with oxygen (alcohol), nitrogen (amide and sulfonamide), and sulfur (thiol) nucleophiles. Mechanistic investigation showed the intermediacy of the ether in this reaction. An electrophilic mechanism is proposed from Hammett correlation.