803730-98-5Relevant articles and documents
A direct and rapid route to α,α-difluoroacylsilanes from trifluoroethanol
Audouard, Christophe,Garayt, Maxime R.,Kérourédan, Erwan,Percy, Jonathan M.,Yang, Hongli
, p. 611 - 623 (2007/10/03)
α,α-Difluoroacylsilanes were synthesised directly from a range of allyl ethers of trifluoroethanol via dehydrofluorination/metallation procedures, followed by thermal [3,3]-sigmatropic rearrangement of the intermediate vinylmetals. The scope and limitatio