80433-84-7

Basic information

• Product Name: (3S,4S)-1,2,3,4-tetrahydrotetraphene-3,4-diol
• CAS NO: 80433-84-7
• Molecular Formula: C₁₈H₁₆O₂
• Molecular Weight: 264.3184
• Mol File: 80433-84-7.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 504.4°C at 760 mmHg
• Flash Point: 245.2°C
• Density: 1.331g/cm³
• Vapor Pressure: 5.38E-11mmHg at 25°C
• Refractive Index: 1.762
• CAS DataBase Reference: (3S,4S)-1,2,3,4-tetrahydrotetraphene-3,4-diol(CAS DataBase Reference)
• NIST Chemistry Reference: (3S,4S)-1,2,3,4-tetrahydrotetraphene-3,4-diol(80433-84-7)
• EPA Substance Registry System: (3S,4S)-1,2,3,4-tetrahydrotetraphene-3,4-diol(80433-84-7)

Safety Data

• Hazardous Substances Data: 80433-84-7(Hazardous Substances Data)

Upstream product

• 80433-85-8 ((1R,2S,5R)-2-Isopropyl-5-methyl-cyclohexyloxy)-acetic acid (3S,4S)-3-[2-((1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyloxy)-acetoxy]-1,2,3,4-tetrahydro-benzo[a]anthracen-4-yl ester 
• 4834-35-9 3-hydroxybenzanthracene 
• 60968-10-7 (+/-)-trans-3,4-dihydroxy-1,2,3,4-tetrahydrobenzanthracene 
• 148190-91-4 (-)-(3R,4R)-trans-3-bromo-4-menthyloxyacetoxy-1,2,3,4-tetrahydrobenzanthracene 
• 148260-35-9 (+)-(3R,4R)-trans-3-bromo-1,2,3,4-tetrahydrobenzanthracen-4-ol 
• 89618-17-7 (+)-(3S,4R)-3,4-epoxy-1,2,3,4-tetrahydrobenzanthracene 
• 64521-17-1 C₁₈H₁₄O 
• 74877-25-1 benzanthracene-3,4-dione 

Downstream Products

• 67335-43-7 benzanthracene-trans-3,4-dihydro-(8S,9S)-diol 
• 80433-93-8 (+)-trans-(3S,4S)-3,4-diacetoxy-3,4-dihydrobenzanthracene 
• 80433-87-0 (+)-trans-(3S,4S)-3,4-diacetoxy-1,2,3,4-tetrahydrobenzanthracene 
• 5133-12-0 4-hydroxybenzoanthracene 
• 67335-42-6 (-)-trans-(3R,4R)-3,4-dihydroxy-3,4-dihydrobenzanthracene 
• 80433-83-6 (+)-trans-(3R,4R)-3,4-dihydroxy-1,2,3,4-tetrahydrobenzanthracene 
• 80433-81-4 (-)-(1S,2R,3R,4S)-3,4-dihydroxy-1,2-epoxy-1,2,3,4-tetrahydrobenzanthracene 
• 80433-78-9 (-)-(1S,2R,3S,4R)-3,4-dihydroxy-1,2-epoxy-1,2,3,4-tetrahydrobenzanthracene 
• 80433-79-0 (+)-(1R,2S,3R,4S)-3,4-dihydroxy-1,2-epoxy-1,2,3,4-tetrahydrobenzanthracene 
• 80446-23-7 (+)-(1R,2S,3S,4R)-3,4-dihydroxy-1,2-epoxy-1,2,3,4-tetrahydrobenzanthracene 
• 80433-92-7 (-)-trans-(3R,4R)-3,4-diacetoxy-3,4-dihydrobenzanthracene 
• 80433-86-9 (-)-trans-(3R,4R)-3,4-diacetoxy-1,2,3,4-tetrahydrobenzanthracene 
• 60968-12-9 Acetic acid (3S,4S)-3-acetoxy-1-bromo-1,2,3,4-tetrahydro-benzo[a]anthracen-4-yl ester 
• 80399-25-3 Acetic acid (3R,4R)-3-acetoxy-1-bromo-1,2,3,4-tetrahydro-benzo[a]anthracen-4-yl ester 

Relevant articles and documents

Synthesis and Spontaneous Racemization of Benzanthracene 3,4-Oxide: Photochemical Oxygen-walk Rearrangements of Arene Oxides of Benzanthracene and Triphenylene to Yield Oxepines

Benzanthracene 3,4-oxide 2, when synthesised from optically pure dibromo ester precursors, was found to have racemized spontaneously and was accompanied by anthraoxepine 14.Photoisomerization of benzanthracene 3,4-oxide 2, triphenylene 1,2-oxide 4 and benzanthracene 1,2-oxide 5 proceeds via an oxygen-walk mechanism to yield anthraoxepine 14, phenanthrooxepine 16 and anthraoxepine 17 respectively.

Synthesis of the Enantiomeric Bay-Region Diol Epoxides of Benzanthracene and Chrysene

Both trans-3,4-dihydroxy-3,4-dihydrobenzanthracene and trans-1,2-dihydroxy-1,2-dihydrochrysene are known proximate carcinogens of their respective hydrocarbons.The present study describes the synthesis of their (+)- and (-)-enantiomers as well as the d