80476-65-9

Basic information

• Product Name: Aceton-[(diisopropylamino)boryl]hydrazon
• CAS NO: 80476-65-9
• Molecular Weight: 183.105
• Mol File: 80476-65-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Aceton-[(diisopropylamino)boryl]hydrazon(CAS DataBase Reference)
• NIST Chemistry Reference: Aceton-[(diisopropylamino)boryl]hydrazon(80476-65-9)
• EPA Substance Registry System: Aceton-[(diisopropylamino)boryl]hydrazon(80476-65-9)

Safety Data

• Hazardous Substances Data: 80476-65-9(Hazardous Substances Data)

Upstream product

• 28049-80-1 bis(diisopropylamino)chloroborane 
• 80476-59-1 Azidobis(diisopropylamino)boran 

Relevant articles and documents

Borimide und Borylnitrene beim Zerfall von Diaminoazidoboranen

Gas phase thermolysis of azidoboranes (R2N)2BN3 (1a, b) at 450-485 deg C gives the products 2a (by retro ene-reaction) and 4b (by intramolecular 1,2-alkylohydrogenation), respectively, both from boron imides R2N-B=N-NR2 (9a, b) as intermediates; furthermore, 3a is isolated from the thermolysis of 1a via a borylnitrene (R2N)2B-N by intramolecular 1,1-alkylohydrogenation.The photolysis of 1a, b generates the borylnitrenes 10a, b as intermediates, which are stabilized by an intermolecular reaction to 7a and 8b, respectively; the nitrene 10a can by trapped by ethyloboration with BEt3.