80516-96-7

Basic information

• Product Name: 1-chloro-4-nonylbenzene
• Synonyms: 1-chloro-4-nonylbenzene
• CAS NO: 80516-96-7
• Molecular Weight: 238.801
• Mol File: 80516-96-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-chloro-4-nonylbenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-chloro-4-nonylbenzene(80516-96-7)
• EPA Substance Registry System: 1-chloro-4-nonylbenzene(80516-96-7)

Safety Data

• Hazardous Substances Data: 80516-96-7(Hazardous Substances Data)

Upstream product

• 104-88-1 4-chlorobenzaldehyde 
• 3391-86-4 1-octen-3-ol 
• 111-83-1 1-bromo-octane 
• 80504-84-3 1-(4-chlorophenyl)-1,3-nonadiene 

Relevant articles and documents

Mechanism of the Solution-Phase Reaction of Alkyl Sulfides Atomic Hydrogen. Reduction via a 9-S-3 Radical Intermediate

The low selectivity of benzyl alkyl sulfide fragmentation subsequent to its reaction with atomic hydrogen is indicative of a reaction that proceeds via an early transition state. The competitive reduction of a series of substituted-benzyl alkyl sulfides was insensitive to the substituent on the aromatic ring (ρ = -0.13, r = 0.99). The relative rates of fragmentation of a series of the substituted-benzyl alkyl sulfides gave a V-shaped Hammett plot. Both electron-donating and electron-withdrawing groups destabilized the transition state (ρ = +0.99, r = 0.999; ρ = -0.82, r = 0.992). Since the relative rates of disappearance of the alkyl benzyl sulfides are not substituent dependent, but the relative rates of fragmentation are, a 9-S-3 intermediate is preferred as the structure leading to products.

DOUBLE BOND FORMATION BY ONE POT PALLADIUM INDUCED REACTIONS BETWEEN ALDEHYDES, ALLYLIC ALCOHOLS AND TRIPHENYLPHOSPHINE

The reaction between several aldehydes, two allylic alcohols and triphenylphosphine under palladium catalysis leads to double bond formation, synthetically parallelizing the Wittig reaction.