80598-98-7

Basic information

• Product Name: N-(methylthio-l propene-l yl) N-trimethylsilyl aniline
• Synonyms: N-(methylthio-l propene-l yl) N-trimethylsilyl aniline
• CAS NO: 80598-98-7
• Molecular Weight: 251.468
• Mol File: 80598-98-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N-(methylthio-l propene-l yl) N-trimethylsilyl aniline(CAS DataBase Reference)
• NIST Chemistry Reference: N-(methylthio-l propene-l yl) N-trimethylsilyl aniline(80598-98-7)
• EPA Substance Registry System: N-(methylthio-l propene-l yl) N-trimethylsilyl aniline(80598-98-7)

Safety Data

• Hazardous Substances Data: 80598-98-7(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 69079-30-7 CH₃SC(C₂H₅)N(C₆H₅) 
• 103-72-0 phenyl isothiocyanate 
• 2955-69-3 N-phenylpropanethioamide 
• 74-88-4 methyl iodide 

Downstream Products

• 3908-55-2 Trimethyl(methylthio)silane 
• 22752-55-2 N-(1-propenylidene)aniline 

Relevant articles and documents

METALLATION ET ALKYLATION DES THIOIMIDOESTERS: APPLICATION EN SYNTHESE

Alkylation of delocalized anions resulting from metallation of N-phenyl thioimidoesters (precursors of dithioesters and thiolesters) takes place on nitrogen with "saturated" thioimidoesters (alkane thiomidates).On the contrary, unsaturated thiomidoesters (α or β-ethylenic, α-arylated) are regioselectively alkylated on the α carbon atom by alkyl or allylic halides.The possibilities for synthesis offered by successive uses of the reactivities of thioimidoester and dithioester functions (allowing in particular two electrophilic additions on two vicinal carbons) are illustrated by syntheses of terpenic compounds lavandual (and lavandulol) and ar-curcumene.