80653-56-1

Basic information

• Product Name: N,N-dimethylsulfonyl-O-methylhydroxylamine
• Synonyms: N,N-dimethylsulfonyl-O-methylhydroxylamine
• CAS NO: 80653-56-1
• Molecular Weight: 203.24
• Mol File: 80653-56-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N,N-dimethylsulfonyl-O-methylhydroxylamine(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-dimethylsulfonyl-O-methylhydroxylamine(80653-56-1)
• EPA Substance Registry System: N,N-dimethylsulfonyl-O-methylhydroxylamine(80653-56-1)

Safety Data

• Hazardous Substances Data: 80653-56-1(Hazardous Substances Data)

Downstream Products

• 2386-57-4 methanesulfonic acid sodium salt 
• 80653-53-8 N-(methoxy)methanesulfonamide 
• 16053-58-0 methanesulfonate 

Relevant articles and documents

Mesylhydroxylamines, VI. Oxidation of N-Mesylhydroxylamines - Vibrational Spectra and Structure of 1,2-Dimesyl-1,2-dimethoxyhydrazine

The oxidation reactions of mesylhydroxylamines proceed mainly via radicals.Oxidation of CH3SO2N(H)OH gives trimesylhydroxylamine (5) probably via the intermediate CH3SO2NO (4).By oxidizing CH3SO2N(H)OCH3 and C6H5SO2N(H)OCH3, derivatives of the hypothetical dihydroxyhydrazine were formed (7a,b).Thermolysis leads to dinitrogen and methyl sulfonate.Oxidation of (CH3SO2)2NOH (1) also gives 5, via 4, but the isomeric CH3SO2N(H)OSO2CH3 is oxidized to nitrate.According to an X-ray structure analysis, 1,2-dimesyl-1,2-dimethoxyhydrazine (7a) crystallizes in the space group P21/n with pyramidally coordinated nitrogen atoms.The vibrational spectra and the structure were discussed in relation to other mesylated nitrogen compounds.