808114-11-6

Basic information

• Product Name: [Cu((diethylaminosalicylaldiminato)nitrobenzene)2]
• CAS NO: 808114-11-6
• Molecular Weight: 688.242
• Mol File: 808114-11-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Cu((diethylaminosalicylaldiminato)nitrobenzene)2](CAS DataBase Reference)
• NIST Chemistry Reference: [Cu((diethylaminosalicylaldiminato)nitrobenzene)2](808114-11-6)
• EPA Substance Registry System: [Cu((diethylaminosalicylaldiminato)nitrobenzene)2](808114-11-6)

Safety Data

• Hazardous Substances Data: 808114-11-6(Hazardous Substances Data)

Upstream product

• 23764-68-3 4-nitroaniline-4-diethylaminosalicylaldehyde schiff base 
• 6046-93-1 copper(II) acetate monohydrate 

Relevant articles and documents

Synthesis, crystal structures, and molecular hyperpolarizabilities of a new Schiff base ligand, and its copper(II), nickel(II), and cobalt(II) metal complexes

A new ligand (HL) obtained from the Schiff base condensation of 4-(diethylamino)salicylaldehyde with 4-nitroaniline is reported, with its nickel(II), copper(II), and cobalt(II) complexes. The crystal structures are reported for the four derivatives. While, NiIIL2 and CuIIL2 are centrosymmetric molecules, Co IIL2 exhibits a pseudo-tetrahedral molecular structure. The quadratic hyperpolarizabilities (β) of HL and CoIIL 2, measured by electric field induced second harmonic (EFISH) technique, are equal to 66 and 110×10-30 cm5esu -1, respectively. Beside a geometric effect (pseudo-Td symmetry), the coordination of the metal center provides an intrinsic enhancement of the NLO response. In addition, an enhancement of the thermal stability of about 60° is found upon metal complexation.