808142-88-3 Usage
Description
Ir(F-Meppy)2(dtbbpy)PF6, also known as [Ir(p-F(Me)ppy)2-(4,4′-dtbbpy)]PF6, is a cyclometalated iridium(III) complex that exhibits unique photophysical and electrochemical properties. This complex is characterized by its ability to absorb visible light and facilitate electron transfer processes, making it a promising candidate for various applications in the field of photocatalysis.
Uses
Used in Photocatalytic Organic Transformations:
Ir(F-Meppy)2(dtbbpy)PF6 is used as a photocatalyst for visible-light mediated photocatalytic organic transformations. Its ability to absorb visible light and generate excited states enables the activation of various organic substrates, leading to the formation of desired products with high efficiency and selectivity.
Used in Energy Conversion Applications:
Due to its strong light absorption and efficient charge separation properties, Ir(F-Meppy)2(dtbbpy)PF6 can be employed in energy conversion applications such as solar cells and photocatalytic water splitting. Its use in these applications can potentially improve the overall efficiency and performance of the energy conversion systems.
Used in Environmental Remediation:
Ir(F-Meppy)2(dtbbpy)PF6 can also be utilized in environmental remediation processes, particularly for the degradation of organic pollutants and contaminants. Its photocatalytic activity under visible light can facilitate the mineralization of harmful substances, contributing to a cleaner and safer environment.
Used in Pharmaceutical Industry:
Although not explicitly mentioned in the provided materials, the unique photophysical and electrochemical properties of Ir(F-Meppy)2(dtbbpy)PF6 may also find potential applications in the pharmaceutical industry. For instance, it could be used as a photosensitizer for photodynamic therapy, where it can generate reactive oxygen species upon light irradiation to selectively destroy cancer cells or harmful microorganisms.
Check Digit Verification of cas no
The CAS Registry Mumber 808142-88-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 8,0,8,1,4 and 2 respectively; the second part has 2 digits, 8 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 808142-88:
(8*8)+(7*0)+(6*8)+(5*1)+(4*4)+(3*2)+(2*8)+(1*8)=163
163 % 10 = 3
So 808142-88-3 is a valid CAS Registry Number.
808142-88-3Relevant articles and documents
Homogeneous catalytic system for photoinduced hydrogen production utilizing iridium and rhodium complexes
Cline, Eric D.,Adamson, Samantha E.,Bernhard, Stefan
, p. 10378 - 10388 (2009/04/14)
An efficient homogeneous catalytic system for the visible-light-induced production of hydrogen from water utilizing cyclometalated iridium(III) and tris-2,2′-bipyridyl rhodium(III) complexes is described. Synthetic modification of the photosensitizer lr(C∧N)2(N∧N)+ and water reduction catalyst Rh(N∧N)33+ creates a family of catalysts with diverse photophysical and electrochemical properties. Parallel screening of the various catalyst combinations and photoreaction conditions allows the rapid development of an optimized photocatalytic system that achieves over 5000 turnovers with quantum yields (1/2 H2 per photon absorbed) greater than 34%. Photophysical and electrochemical characterization of the optimized system reveals that the reductive quenching pathway provides the necessary driving force for the formation of [Rh(N∧N)2]0, the active catalytic species for the reduction of water to produce hydrogen. Tests for system poisoning with mercury or CS2 provide strong evidence that the system is a true homogeneous system for photocatalytic hydrogen production.
