80816-37-1

Basic information

• Product Name: C₁₉H₁₆ClNO₃S₂
• Synonyms: C₁₉H₁₆ClNO₃S₂
• CAS NO: 80816-37-1
• Molecular Weight: 405.926
• Mol File: 80816-37-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: C₁₉H₁₆ClNO₃S₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₉H₁₆ClNO₃S₂(80816-37-1)
• EPA Substance Registry System: C₁₉H₁₆ClNO₃S₂(80816-37-1)

Safety Data

• Hazardous Substances Data: 80816-37-1(Hazardous Substances Data)

Upstream product

• 24702-38-3 S-(p-chlorophenyl)-S-phenyl-N-(p-tolylsulfonyl)sulfilimine 

Relevant articles and documents

A CONVENIENT PREPARATION OF N-(ARENESULFONYL)SULFOXIMINES BY OXIDATION OF N-(ARENESULFONYL)SULFILIMINES WITH SODIUM HYPOCHLORITE IN A TWO PHASE SYSTEM

N-(Arenesulfonyl)sulfilimines can be oxidized to the corresponding sulfoximines in high yields with sodium hypochlorite in an AcOEt-H2O two phase system in the presence of quaternary ammonium salts as catalysts.

Oxidation of S,S-Diaryl-N-(p-tolylsulfonyl)sulfilimines and N-Unsubstituted S,S-Diaryl-sulfilimines with Potassium Hyperoxide Anion Radical (O2-.) in the Presence of 1-Bromopropane, Benzoyl Chloride, p-Tolylsulfonyl Chloride, Carbon Tetrachloride, Chloroform, or Dichloromethane in

The reaction of S,S-diaryl-N-(p-tolylsulfonyl)sulfilimines and N-unsubstituted diaryl-sulfilimines with hydroperoxide anion radical (O2-.) in the presence of 18-crown-6 as a catalyst together with 1-bromopropane/benzene, benzoyl chloride/benzene, p-tolylsulfonyl chloride/benzene, carbon tetrachloride, chloroform, or dichloromethane, gave the corresponding sulfoximines, through nucleophilic oxidation with an intermadiary dioxy species formed upon treatment of organic halides with potassium hyperoxide (KO2).