80845-81-4

Basic information

• Product Name: Heptanoic acid, 3-(1-methylethyl)-6-oxo-, (R)-
• CAS NO: 80845-81-4
• Molecular Formula: C10H18O3
• Molecular Weight: 186.251
• Mol File: 80845-81-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Heptanoic acid, 3-(1-methylethyl)-6-oxo-, (R)-(CAS DataBase Reference)
• NIST Chemistry Reference: Heptanoic acid, 3-(1-methylethyl)-6-oxo-, (R)-(80845-81-4)
• EPA Substance Registry System: Heptanoic acid, 3-(1-methylethyl)-6-oxo-, (R)-(80845-81-4)

Safety Data

• Hazardous Substances Data: 80845-81-4(Hazardous Substances Data)

Upstream product

• 1195-31-9 (+)-p-menth-1-ene 

Downstream Products

• 10264-56-9 3-(R)-(2'-methylethyl)-cyclopentanone 
• 91208-70-7 <2(R,S),5(E,Z),9R>-6-Methyl-9-(1-methylethyl)-2-(phenylthio)-11-<(p-tolylsulfonyl)oxy>-5-undecenenitrile 
• 91201-50-2 Methyl <1(R,S),4(E,Z),8R>-5-Methyl-8-(1-methylethyl)-1-(phenylthio)-4-cyclodecenecarboxylate 
• 91201-49-9 <1(R,S),4(E,Z),8R>-5-Methyl-8-(1-methylethyl)-1-(phenylthio)-4-cyclodecenecarbonitrile 
• 91201-47-7 <2(R,S),5(E,Z),9R>-11-Hydroxy-6-methyl-9-(1-methylethyl)-2-(phenylthio)-5-undecenenitrile 

Relevant articles and documents

Ruthenium Tetroxide Oxidation of Alkenes. A More Complete Picture

The ruthenium tetroxide oxidation of some linear and cyclic alkenes, representatives of five substitution patterns, has been performed in acetone-water (5:1) solution at -70 deg C using stoichiometric ammounts of the oxidant.The main reaction products are 1,2-diols and/or α-ketols depending on the nature of the substrate little amounts of scission products, aldehydes and/or carboxylic acids, are also obtained.Generally 1,2-diols predominate over α-ketols except in the oxidation of (-)-α-pinene that afforded the α-ketol in 51percent yield while no trace of the corresponding 1,2-diol was detected.All reactions prceeded through the formation of unstable brownish precipitates, presumably the intermediate ruthenium (VI) esters, which easily decomposed during the work-up step.Results from oxidation of trans-7-tetradecene and cis and trans-11-tetradecenyl acetate indicated that the reaction was syn stereospecific.In some cases, 1,3-dioxolane products, formed by condensation of the 1,2-diol and the aldehyde materials, were also obtained among the reaction products.Their possible origin is briefly discussed.