81098-40-0

Basic information

• Product Name: 6-Methyl-2,2,4,4-tetrakis-(2,2,2-trifluoro-ethoxy)-2λ⁵,4λ⁵,6λ⁵-[1,3,5,2,4,6]triazatriphosphinine
• CAS NO: 81098-40-0
• Molecular Weight: 547.114
• Mol File: 81098-40-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 6-Methyl-2,2,4,4-tetrakis-(2,2,2-trifluoro-ethoxy)-2λ⁵,4λ⁵,6λ⁵-[1,3,5,2,4,6]triazatriphosphinine(CAS DataBase Reference)
• NIST Chemistry Reference: 6-Methyl-2,2,4,4-tetrakis-(2,2,2-trifluoro-ethoxy)-2λ⁵,4λ⁵,6λ⁵-[1,3,5,2,4,6]triazatriphosphinine(81098-40-0)
• EPA Substance Registry System: 6-Methyl-2,2,4,4-tetrakis-(2,2,2-trifluoro-ethoxy)-2λ⁵,4λ⁵,6λ⁵-[1,3,5,2,4,6]triazatriphosphinine(81098-40-0)

Safety Data

• Hazardous Substances Data: 81098-40-0(Hazardous Substances Data)

Upstream product

• 420-87-1 sodium 2,2,2-trifluoroethanolate 
• 67-63-0 isopropyl alcohol 
• 917-54-4 methyllithium 

Relevant articles and documents

Reactivity of Hexachlorocyclotriphosphazene towards Alkyl-lithium Reagents

Reactions of (NPCl2)3 with LiMe or LiBut and excess of propan-2-ol at -60 deg C in tetrahydrofuran lead to complex reaction mixtures containing cyclic derivatives in 80-90percent yield.The composition of each reaction mixture has been analyzed by 1H and 31P n.m.r. spectrometry.The n.m.r. data thus obtained indicate the presence of a novel cyclophosphazene, viz.NP(H)OPri(NPCl2)2 and several alkyl-substituted cyclophosphazenes.Typical compounds were isolated and characterized as their 2,2,2-trifluoroethoxy-substituted derivatives.The structural characterizations of the reaction products are described together with the appropriate reaction pathways, based on an initial metal-halogen exchange process.