81168-16-3

Basic information

• Product Name: Benzenemethanol, 2-[2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]ethyl]-
• CAS NO: 81168-16-3
• Molecular Formula: C15H26O2Si
• Molecular Weight: 266.456
• Mol File: 81168-16-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, 2-[2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]ethyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, 2-[2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]ethyl]-(81168-16-3)
• EPA Substance Registry System: Benzenemethanol, 2-[2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]ethyl]-(81168-16-3)

Safety Data

• Hazardous Substances Data: 81168-16-3(Hazardous Substances Data)

Upstream product

• 6346-00-5 2-(2-hydroxyethyl)benzyl alcohol 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 89-51-0 Homophthalic acid 

Downstream Products

• 130217-43-5 Dimethyl 2,5-Dihydro-1-benzyloxycarbonyl-2-<2-<2-(t-butyldimethylsilyloxyethyl)phenyl>>pyrrole-3,4-dicarboxylate 
• 130217-46-8 Dimethyl 2,5-Dihydro-1-benzyloxycarbonyl-2-<2-(2-chloroethyl)phenyl>pyrrole-3,4-dicarboxylate 
• 130217-47-9 [1-{2-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-phenyl}-meth-(E)-ylidene]-trimethylsilanylmethyl-amine 
• 81168-10-7 2-<2-(t-Butyldimethylsilyloxy)ethyl>benzaldehyde 

Relevant articles and documents

Application of the intramolecular yamamoto vinylogous aldol reaction to the synthesis of macrolides

An intramolecular version of the Yamamoto vinylogous aldol reaction, a method that employs the bulky Lewis acid ATPH to control the site of aldolization, is described. This macrocyclization process is effective for the construction of 10-, 12-, and 14-mem

Synthesis of 3,9b-Dihydro-5H-pyrroloisoindoles and 3,5,6,10b-Tetrahydropyrroloisoquinolines with 1,3-Dipolar Cycloaddition Reactions.

The title classes of compounds have been prepared using a sequence of two ring-forming reactions.Initial 1,3-dipolar cycloaddition with an azomethine ylide gave N-acylated 3-pyrrolines which were further elaborated to the target compounds by a tandem deprotection/cyclization reaction.