81171-54-2

Basic information

• Product Name: (2-Chloro-1-methoxy-2-methyl-3-phenyl-cyclopropoxy)-trimethyl-silane
• CAS NO: 81171-54-2
• Molecular Weight: 284.858
• Mol File: 81171-54-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2-Chloro-1-methoxy-2-methyl-3-phenyl-cyclopropoxy)-trimethyl-silane(CAS DataBase Reference)
• NIST Chemistry Reference: (2-Chloro-1-methoxy-2-methyl-3-phenyl-cyclopropoxy)-trimethyl-silane(81171-54-2)
• EPA Substance Registry System: (2-Chloro-1-methoxy-2-methyl-3-phenyl-cyclopropoxy)-trimethyl-silane(81171-54-2)

Safety Data

• Hazardous Substances Data: 81171-54-2(Hazardous Substances Data)

Upstream product

• 101-41-7 benzeneacetic acid methyl ester 
• 75-34-3 1,1-dichloroethane 
• 40195-27-5 (1-methoxy-2-phenylvinyloxy)trimethylsilane 

Downstream Products

• 21370-57-0 methyl (Z)-2-methyl-3-phenylprop-2-enoate 
• 22946-43-6 (E)-methyl-2-methyl-3-phenylacrylate 
• 21370-57-0 methyl 2-methyl-3-phenylacrylate 

Relevant articles and documents

ETUDE DE LA REACTION CHLOROCARBENE-ACETALS DE CETENES. I. SYNTHESE D'ESTERS α,β-ETHYLENIQUES.

The reaction of chloro, chloromethyl and chlorophenyl carbenoids with ketene alkylsilylacetals has been studied.Excellent yields of cyclopropanation were observed and the unstable chlorocyclopropanone acetals formed were thermally rearranged in high yield into α-substituted α,β-ethylenic esters.This new method for the synthesis of unsaturated esters appeared complementary of the known-ones.