81256-03-3

Basic information

• Product Name: 1,4-Pentadien-3-ol, 1-phenyl-5-(trimethylsilyl)-, (E,E)-
• CAS NO: 81256-03-3
• Molecular Formula: C14H20OSi
• Molecular Weight: 232.398
• Mol File: 81256-03-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1,4-Pentadien-3-ol, 1-phenyl-5-(trimethylsilyl)-, (E,E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4-Pentadien-3-ol, 1-phenyl-5-(trimethylsilyl)-, (E,E)-(81256-03-3)
• EPA Substance Registry System: 1,4-Pentadien-3-ol, 1-phenyl-5-(trimethylsilyl)-, (E,E)-(81256-03-3)

Safety Data

• Hazardous Substances Data: 81256-03-3(Hazardous Substances Data)

Upstream product

• 85533-19-3 1-benzenesulfinyl-2-trimethylsilylethane 
• 17988-59-9 phenyl 2-(trimethylsilyl)ethyl sulfide 
• 14371-10-9 (E)-3-phenylpropenal 
• 42201-74-1 <β-(Trimethylsilyl)vinyl>magnesium bromide 
• 41309-43-7 (2-bromovinyl)trimethylsilane 

Downstream Products

• 81255-96-1 4-phenyl-2-cyclopenten-1-one 
• 59376-62-4 (1E,4E)-1-(trimethylsilyl)-5-phenylpenta-1,4-dien-3-one 

Relevant articles and documents

1-LITHIO-1-BENZENESULFINYL-2-TRIMETHYLSILYLETHANE AS A 2-TRIMETHYLSILYLVINYL ANION EQUIVALENT IN REACTIONS WITH ALHEDYDES, KETONES AND EPOXIDES

Aldehydes, ketones and epoxides give adducts with 1-lithio-1-benzenesulfinyl-2-trimethylsilylethane which upon neutralization eliminate benezenesulfenic acid efficiently at 76 deg C to yield trans-3-(trimethylsilyl)allyl alcohols and trans-4-(trimethylsilyl)-3-alken-1-ols.

Silicon-Directed Nazarov Cyclization

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