81369-81-5Relevant articles and documents
A Highly Enantiocontrolled Strategy for the Synthesis of Benzylic Quaternary Carbon Centers. A Formal Total Synthesis of (-)-Mesebrine
Nemoto, Hideo,Tanabe, Tetsuro,Fukumoto, Keiichiro
, p. 6785 - 6790 (2007/10/03)
A remarkable substituent effect by a trimethylsilyl group was observed on the enantioselectivity of the tandem asymmetric epoxidation and enantiospecific ring expansion of 2-cyclopropylidene-2-(4,5-dimethoxy-2-(trimethylsilyl)phenyl)ethanol (24), affordin
ENANTIOSELECTIVE SYNTHESIS OF NATURAL MESEMBRINE USING (D)-MANNITOL AS A CHIRAL TEMPLATE, A MODEL STUDY FOR THE ENANTIOSELECTIVE SYNTHESIS OF THE AMARYLLIDACEAE ALKALOIDS
Takano, Seiichi,Imamura, Yoko,Ogasawara, Kunio
, p. 4479 - 4482 (2007/10/02)
Enantioselective synthesis of (-)-mesembrine (1) has been achieved using (D)-mannitol with the intention of developing the enantioselective synthesis of the Amaryllidaceae alkaloids.