81439-35-2Relevant articles and documents
Some reactions of pentafluorosulfur hypofluorite and trifluoromethyl hypofluorite
Pass,Roberts
, p. 1016 - 1019 (2008/10/08)
The reaction of peutafluorosulfur hypofluorite with sulfur dioxide in the liquid phase gives SF5OSO2F. Pentafluorosulfur hypofluorite reacts with sulfur tetrafluoride to give SF5OSF5, SF5OOSF5, and SF5OSF4OSF5, while a similar reaction in the presence of oxygen gives SF5OSF4OOSF5 and SF5OSF4OOSF4OSF5 as additional products. These new peroxides react with benzene to give C6H5OSF4OSF5. The reaction of trifluoromethyl hypofluorite with sulfur tetrafluoride gives CF3OSF5 as the only product. Trifluoromethyl hypofluorite, sulfur tetrafluoride, and oxygen react to give CF3OSF4OSF5, CF3OSF4OOSF5, and a compound believed to be CF3OSF4OOSF4OCF3. A reaction scheme which accounts for these products is proposed.
