81488-13-3Relevant articles and documents
IODINE INDUCED TRANSFER OF DIALKYLVINYLBORANES PRODUCED BY THE HYDRIDATION OF DIALKYLHALOBORANES IN THE PRESENCE OF 1-ALKYNES. GENERALIZATION OF THE ZWEIFEL cis-ALKENE SYNTHESIS
Kulkarni, Surendra U.,Basavaiah, D.,Brown, Herbert C.
, p. C1 - C5 (1982)
Dialkylvinylboranes, prepared conveniently via the hydridation of dialkylhaloboranes in the presence of terminal alkynes, react with iodine in the presence of base at reduced temperatures to form teh corresponding cis-disubstituted alkenes.This development greatly increases the generality of the elegant Zweifel cis-olefin synthesis.